|
|
Anisotropic metal-insulator transition in strained VO2(B) single crystal |
Zecheng Ma(马泽成)1,†, Shengnan Yan(闫胜楠)1,†, Zenglin Liu(刘增霖)1, Tao Xu(徐涛)2, Fanqiang Chen(陈繁强)1, Sicheng Chen(陈思成)1, Tianjun Cao(曹天俊)1, Litao Sun(孙立涛)2, Bin Cheng(程斌)3, Shi-Jun Liang(梁世军)1,‡, and Feng Miao(缪峰)1,§ |
1 Institute of Brain-Inspired Intelligence, National Laboratory of Solid State Microstructures, School of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China; 2 SEU-FEI Nano-Pico Center, Key Laboratory of MEMS of Ministry of Education, Southeast University, Nanjing 210096, China; 3 Institute of Interdisciplinary of Physical Sciences, School of Science, Nanjing University of Science and Technology, Nanjing 210094, China |
|
|
Abstract Mechanical strain can induce noteworthy structural and electronic changes in vanadium dioxide, imparting substantial scientific importance to both the exploration of phase transitions and the development of potential technological applications. Unlike the traditional rutile (R) phase, bronze-phase vanadium dioxide [VO$_{2}$(B)] exhibits an in-plane anisotropic structure. When subjected to stretching along distinct crystallographic axes, VO$_{2}$(B) may further manifest the axial dependence in lattice-electron interactions, which is beneficial for gaining insights into the anisotropy of electronic transport. Here, we report an anisotropic room-temperature metal-insulator transition in single-crystal VO$_{2}$(B) by applying in-situ uniaxial tensile strain. This material exhibits significantly different electromechanical responses along two anisotropic axes. We reveal that such an anisotropic electromechanical response mainly arises from the preferential arrangement of a strain-induced unidirectional stripe state in the conductive channel. This insulating stripe state could be attributed to the in-plane dimerization within the distorted zigzag chains of vanadium atoms, evidenced by strain-modulated Raman spectra. Our work may open up a promising avenue for exploiting the anisotropy of metal-insulator transition in vanadium dioxide for potential technological applications.
|
Received: 15 February 2024
Revised: 20 March 2024
Accepted manuscript online: 03 April 2024
|
PACS:
|
71.30.+h
|
(Metal-insulator transitions and other electronic transitions)
|
|
72.80.Ga
|
(Transition-metal compounds)
|
|
78.20.-e
|
(Optical properties of bulk materials and thin films)
|
|
07.10.Pz
|
(Instruments for strain, force, and torque)
|
|
Fund: Project supported by the National Key R&D Program of China (Grant No. 2023YFF1203600), the National Natural Science Foundation of China (Grant Nos. 62122036, 62034004, 12322407, 61921005, and 12074176), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB44000000). |
Corresponding Authors:
Shi-Jun Liang, Feng Miao
E-mail: sjliang@nju.edu.cn;miao@nju.edu.cn
|
Cite this article:
Zecheng Ma(马泽成), Shengnan Yan(闫胜楠), Zenglin Liu(刘增霖), Tao Xu(徐涛), Fanqiang Chen(陈繁强), Sicheng Chen(陈思成), Tianjun Cao(曹天俊), Litao Sun(孙立涛), Bin Cheng(程斌), Shi-Jun Liang(梁世军), and Feng Miao(缪峰) Anisotropic metal-insulator transition in strained VO2(B) single crystal 2024 Chin. Phys. B 33 067103
|
[1] Cao J, Ertekin E, Srinivasan V, Fan W, Huang S, Zheng H, Yim J W, Khanal D R, Ogletree D F, Grossman J C and Wu J 2009 Nat. Nanotechnol. 4 732 [2] Tselev A, Luk’yanchuk I A, Ivanov I N, Budai J D, Tischler J Z, Strelcov E, Kolmakov A and Kalinin S V 2010 Nano Lett. 10 4409 [3] Hong B, Yang Y, Hu K, Dong Y, Zhou J, Zhang Y, Zhao W, Luo Z and Gao C 2019 Appl. Phys. Lett. 115 251605 [4] Liu K, Lee S, Yang S, Delaire O and Wu J 2018 Mater. Today 21 875 [5] Shvets P, Dikaya O, Maksimova K and Goikhman A 2019 J. Raman Spectrosc. 50 1226 [6] Hu P, Hu P, Vu T D, Li M, Wang S, Ke Y, Zeng X, Mai L and Long Y 2023 Chem. Rev. 123 4353 [7] Aetukuri N B, Gray A X, Drouard M, Cossale M, Gao L, Reid A H, Kukreja R, Ohldag H, Jenkins C A, Arenholz E, Roche K P, Dürr H A, Samant M G and Parkin S S P 2013 Nat. Phys. 9 661 [8] Fan L L, Chen S, Luo Z L, Liu Q H, Wu Y F, Song L, Ji D X, Wang P, Chu W S, Gao C, Zou C W and Wu Z Y 2014 Nano Lett. 14 4036 [9] Liu M K, Wagner M, Abreu E, Kittiwatanakul S, McLeod A, Fei Z, Goldflam M, Dai S, Fogler M M, Lu J, Wolf S A, Averitt R D and Basov D N 2013 Phys. Rev. Lett. 111 096602 [10] Yang M, Yang Y, Bin H, Wang L, Hu K, Dong Y, Xu H, Huang H, Zhao J, Chen H, Song L, Ju H, Zhu J, Bao J, Li X, Gu Y, Yang T, Gao X, Luo Z and Gao C 2016 Sci. Rep. 6 23119 [11] Hu K, Yang Y, Hong B, Zhao J, Luo Z, Li X, Zhang X, Gu Y, Gao X and Gao C 2017 J. Alloys Compd. 699 575 [12] Jones A C, Berweger S, Wei J, Cobden D and Raschke M B 2010 Nano Lett. 10 1574 [13] Hu B, Ding Y, Chen W, Kulkarni D, Shen Y, Tsukruk V V and Wang Z L 2010 Adv. Mater. 22 5134 [14] Cao J, Gu Y, Fan W, Chen L Q, Ogletree D F, Chen K, Tamura N, Kunz M, Barrett C, Seidel J and Wu J 2010 Nano Lett. 10 2667 [15] Guo H, Chen K, Oh Y, Wang K, Dejoie C, Syed Asif S A, Warren O L, Shan Z W, Wu J and Minor A M 2011 Nano Lett. 11 3207 [16] Park J H, Coy J M, Kasirga T S, Huang C, Fei Z, Hunter S and Cobden D H 2013 Nature 500 431 [17] Oka Y, Yao T, Yamamoto N, Ueda Y and Hayashi A 1993 J. Solid State Chem. 105 271 [18] Corr S A, Grossman M, Shi Y, Heier K R, Stucky G D and Seshadri R 2009 J. Mater. Chem. 19 4362 [19] Lourembam J, Srivastava A, La-o-vorakiat C, Rotella H, Venkatesan T and Chia E E 2015 Sci. Rep. 5 9182 [20] Popuri S R, Artemenko A, Decourt R, Josse M, Chung U C, Michau D, Maglione M, Villesuzanne A and Pollet M 2015 J. Phys. Chem. C 119 25085 [21] Lourembam J, Srivastava A, La-o-Vorakiat C, Cheng L, Venkatesan T and Chia E E M 2016 Sci. Rep. 6 25538 [22] Zhang Y, Wang X, Zhou Y, Lai H, Liu P, Chen H, Wang X and Xie W 2021 Nano Lett. 22 485 [23] Wang Y, Zhu J, Yang W, Wen T, Pravica M, Liu Z, Hou M, Fei Y, Kang L, Lin Z, Jin C and Zhao Y 2016 Nat. Commun. 7 12214 [24] Théobald F, Cabala R and Bernard J 1976 J. Solid State Chem. 17 431 [25] Liu J, Li Q, Wang T, Yu D and Li Y 2004 Angew. Chem. Int. Ed. 43 5048 [26] Wang Y, Wang C, Liang S J, Ma Z C, Xu K, Liu X W, Zhang L L, Admasu A S, Cheong S W, Wang L Z, Chen M Y, Liu Z L, Cheng B, Ji W and Miao F 2020 Adv. Mater. 32 2004533 [27] Zhang Z, Li L, Horng J, Wang N Z, Yang F, Yu Y, Zhang Y, Chen G, Watanabe K, Taniguchi T, Chen X H, Wang F and Zhang Y 2017 Nano Lett. 17 6097 [28] An C, Xu Z, Shen W, Zhang R, Sun Z, Tang S, Xiao Y F, Zhang D, Sun D, Hu X, Hu C, Yang L and Liu J 2019 ACS Nano 13 3310 [29] Shi R, Chen Y, Cai X, Lian Q, Zhang Z, Shen N, Amini A, Wang N and Cheng C 2021 Nat. Commun. 12 4214 [30] Wang X J, Li H D, Fei Y J, Wang X, Xiong Y Y, Nie Y X and Feng K A 2001 Appl. Surface Sci. 177 8 [31] Huang C, Chen L, Xu G and Miao L 2012 J. Sol-Gel Sci. Technol. 63 103 [32] Zhang S, Fu J, Su Q, Wu L and Li X 2016 Rare Metal Mater. Eng. 45 1374 [33] Zallen R and Slade M 1974 Phys. Rev. B 9 1627 [34] Hsueh H C, Warren M C, Vass H, Ackland G J, Clark S J and Crain J 1996 Phys. Rev. B 53 14806 [35] Chen Y, Zhang S, Ke F, Ko C, Lee S, Liu K, Chen B, Ager J W, Jeanloz R, Eyert V and Wu J 2017 Nano Lett. 17 2512 [36] Lee D, Chung B, Shi Y, Kim G Y, Campbell N, Xue F, Song K, Choi S Y, Podkaminer J P, Kim T H, Ryan P J, Kim J W, Paudel T R, Kang J H, Spinuzzi J W, Tenne D A, Tsymbal E Y, Rzchowski M S, Chen L Q, Lee J and Eom C B 2018 Science 362 1037 [37] Sohn J I, Joo H J, Ahn D, Lee H H, Porter A E, Kim K, Kang D J and Welland M E 2009 Nano Lett. 9 3392 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
Altmetric
|
blogs
Facebook pages
Wikipedia page
Google+ users
|
Online attention
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.
View more on Altmetrics
|
|
|