Interfaces of high-efficiency kesterite Cu2ZnSnS(e)4 thin film solar cells

doi:10.1088/1674-1056/27/1/018803

Abstract

Cu₂ZnSnS(e)₄ (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu₂ZnSn(S,Se)₄ (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se₂ (CIGS) solar cells. One crucial reason is the recombination at interfaces. In recent years, large amount investigations have been done to analyze the interfacial problems and improve the interfacial properties via a variety of methods. This paper gives a review of progresses on interfaces of CZTS(e) solar cells, including:(i) the band alignment optimization at buffer/CZTS(e) interface, (ii) tailoring the thickness of MoS(e)₂ interfacial layers between CZTS(e) absorber and Mo back contact, (iii) the passivation of rear interface, (iv) the passivation of front interface, and (v) the etching of secondary phases.

Keywords: Cu₂ZnSnS₄ solar cells kesterite interface passivation

Received: 26 September 2017
Revised: 25 November 2017
Accepted manuscript online:

PACS:	88.40.H-	(Solar cells (photovoltaics))
	79.60.Jv	(Interfaces; heterostructures; nanostructures)
	73.40.Cg	(Contact resistance, contact potential)
	88.40.hj	(Efficiency and performance of solar cells)

Fund:

Project supported by the National Natural Science Foundation of China (Grant Nos. 51572132, 51372121, and 61674082), the Natural Science Foundation of Key Project of Tianjin City, China (Grant No. 16JCZDJC30700), the YangFan Innovative and Entrepreneurial Research Team Project of China (Grant No. 2014YT02N037), and 111 Project, China (Grant No. B16027).

Corresponding Authors: Jianping Ao, Yi Zhang
E-mail: aojp@nankai.edu.cn;yizhang@nankai.edu.cn

Cite this article:

Shoushuai Gao(高守帅), Zhenwu Jiang(姜振武), Li Wu(武莉), Jianping Ao(敖建平), Yu Zeng(曾玉), Yun Sun(孙云), Yi Zhang(张毅) Interfaces of high-efficiency kesterite Cu₂ZnSnS(e)₄ thin film solar cells 2018 Chin. Phys. B 27 018803

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