Theoretical study on the kesterite solar cells based on Cu2ZnSn(S,Se)4 and related photovoltaic semiconductors

doi:10.1088/1674-1056/27/1/018806

Abstract

The kesterite thin film solar cells based on the quaternary Cu₂ZnSnS₄ and Cu₂ZnSnSe₄ and their alloys Cu₂ZnSn(S,Se)₄ have been considered as environment-friendly and non-toxic alternatives to the currently commercialized CdTe and Cu(In,Ga)Se₂ thin film solar cells. From the theoretical point of view, we will review how the group I₂-Ⅱ-IV-VI₄ quaternary compound semiconductors are derived from the binary CdTe and the ternary CuInSe₂ or CuGaSe₂ through the cation mutation, and how the crystal structure and electronic band structure evolve as the component elements change. The increased structural and chemical freedom in these quaternary semiconductors opens up new possibility for the tailoring of material properties and design of new light-absorber semiconductors. However, the increased freedom also makes the development of high-efficiency solar cells more challenging because much more intrinsic point defects, secondary phases, surfaces, and grain-boundaries can exist in the thin films and influence the photovoltaic performance in a way different from that in the conventional CdTe and Cu(In,Ga)Se₂ solar cells. The experimental characterization of the properties of defects, secondary phase, and grain-boundaries is currently not very efficient and direct, especially for these quaternary compounds. First-principles calculations have been successfully used in the past decade for studying these properties. Here we will review the theoretical progress in the study of the mixed-cation and mixed-anion alloys of the group I₂-Ⅱ-IV-VI₄ semiconductors, defects, alkaline dopants, and grain boundaries, which provided very important information for the optimization of the kesterite solar cell performance.

Keywords: kesterite thin film solar cells Cu₂ZnSnS₄ and Cu₂ZnSnSe₄ first-principles calculations defects and dopants

Received: 16 October 2017
Revised: 17 November 2017
Accepted manuscript online:

PACS:	88.40.H-	(Solar cells (photovoltaics))
	71.20.Nr	(Semiconductor compounds)
	61.50.Ah	(Theory of crystal structure, crystal symmetry; calculations and modeling)
	71.20.-b	(Electron density of states and band structure of crystalline solids)

Fund:

Project supported by the National Key Research and Development Program of China (Grant No. 2016YFB0700700), the National Natural Science Foundation of China (Grant Nos. 61574059 and 61722402), Shu-Guang Program, China (Grant No. 15SG20), and CC of ECNU, China.

Corresponding Authors: Shiyou Chen
E-mail: chensy@ee.ecnu.edu.cn

Cite this article:

Dingrong Liu(刘定荣), Dan Han(韩丹), Menglin Huang(黄梦麟), Xian Zhang(张弦), Tao Zhang(张涛), Chenmin Dai(戴称民), Shiyou Chen(陈时友) Theoretical study on the kesterite solar cells based on Cu₂ZnSn(S,Se)₄ and related photovoltaic semiconductors 2018 Chin. Phys. B 27 018806

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Theoretical study on the kesterite solar cells based on Cu2ZnSn(S,Se)4 and related photovoltaic semiconductors

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Theoretical study on the kesterite solar cells based on Cu₂ZnSn(S,Se)₄ and related photovoltaic semiconductors