Magnetic properties and magnetocaloric effects in HoPd intermetallic

doi:10.1088/1674-1056/24/3/037503

Abstract A large reversible magnetocaloric effect accompanied by a second order magnetic phase transition from PM to FM is observed in the HoPd compound. Under the magnetic field change of 0-5 T, the magnetic entropy change -ΔS_M^max and the refrigerant capacity RC for the compound are evaluated to be 20 J/(kg · K) and 342 J/kg, respectively. In particular, large -ΔS_M^max (11.3 J/(kg · K)) and RC (142 J/kg) are achieved under a low magnetic field change of 0-2 T with no thermal hysteresis and magnetic hysteresis loss. The large reversible magnetocaloric effect (both the large -ΔS_M and the high RC) indicates that HoPd is a promising material for magnetic refrigeration at low temperature.

Keywords: magnetocaloric effect magnetic entropy change magnetic phase transformation

Received: 09 September 2014
Revised: 20 October 2014
Accepted manuscript online:

PACS:	75.30.Sg	(Magnetocaloric effect, magnetic cooling)
	65.40.gd	(Entropy)
	75.30.Kz	(Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51322605, 11104337, 51271192, and 11274357) and the Knowledge Innovation Project of the Chinese Academy of Sciences.

Corresponding Authors: Shen Jun
E-mail: jshen@mail.ipc.ac.cn

Cite this article:

Mo Zhao-Jun (莫兆军), Shen Jun (沈俊), Gao Xin-Qiang (高新强), Liu Yao (刘瑶), Wu Jian-Feng (吴剑峰), Shen Bao-Gen (沈保根), Sun Ji-Rong (孙继荣) Magnetic properties and magnetocaloric effects in HoPd intermetallic 2015 Chin. Phys. B 24 037503

[1]	Gschneidner Jr K A, Pecharsky V K and Tsokol A O 2005 Rep. Prog. Phys. 68 1479
[2]	Franco V, Blázquez J S and Conde A 2006 Appl. Phys. Lett. 89 222512
[3]	Shen B G, Sun J R, Hu F X, Zhang H W and Cheng Z H 2009 Adv. Mater. 21 4545
[4]	Shen B G, Hu F X, Dong Q Y and Sun J R 2013 Chin. Phys. B 22 017502
[5]	Gutfleisch O, Willard M A, Brück E, Chen C H, Sankar S G and Liu J P 2011 Adv. Mater. 23 821
[6]	Hu F X, Shen B G, Sun J R, Chen Z H, Rao G H and Zhang X X 2001 Appl. Phys. Lett. 78 3675
[7]	Hu F X, Shen B G, Sun J R and Zhang X X 2000 Chin. Phys. 9 550
[8]	Shen J, Gao B, Yan L Q, Li Y X, Zhang H W, Hu F X and Sun J R 2007 Chin. Phys. 16 3848
[9]	Tegus O, Brück E, Buschow K H J and de Boer F R 2002 Nature 415 150
[10]	Tegus O, Bao L H and Song L 2013 Chin. Phys. B 22 037506
[11]	Geng Y X, Tegus O and Bi L G 2012 Chin. Phys. B 21 037504
[12]	Pecharsky V K, Holm A P, Gschneidner, Jr K A and R Rink 2003 Phys. Rev. Lett. 91 198
[13]	Pecharsky V K and Gschneidenr Jr K A 1997 Appl. Phys. Lett. 70 3299
[14]	Zou J D 2012 Chin. Phys. B 21 037503
[15]	Hu F X, Shen B G and J R Sun 2000 Appl. Phys. Lett. 76 3460
[16]	Tishin A M, Spichkin Y I, in: Coey J M D, Tilley D R and Vij D R (Eds.) 2003 The Magnetocaloric Effect and its Applications (Bristol: Institute of Physics Publishing)
[17]	Barclay J A and W A Steyert 1982 Cryogenics 22 73
[18]	DiPirro M, Tuttle J, Jackson M, Canavan E, Warner B and Shirron P 2006 Adv. Cryog. Eng. 51A 969
[19]	Li L, Nishimura K, Hutchison W D, Qian Z, Huo D and Namiki T 2012 Appl. Phys. Lett. 100 152403
[20]	Li L, Hutchison W D, Huo D X, Namiki T, Qian Z H and Nishimura K 2012 Scr. Mater. 67 237
[21]	Samanta T, Das I and Banerjee S 2007 Appl. Phys. Lett. 91 152506
[22]	Chen J, Shen B G, Dong Q Y, Hu F X and Sun J R 2010 Appl. Phys. Lett. 96 152501
[23]	Mo Z J, Shen J, Yan L Q, Tang C C, Lin J, Wu J F, Sun J R, Wang L C, Zheng X Q and Shen B G 2013 Appl. Phys. Lett. 103 052409
[24]	Mo Z J, Shen J, Yan L Q, Wu J F, Wang L C, Lin J, Tang C C and Shen B G 2013 Appl. Phys. Lett. 102 192407
[25]	Zhang H, Shen B G, Xu Z Y, Shen J, Hu F X, Sun J R and Long Y 2013 Appl. Phys. Lett. 102 092401
[26]	Zhang X X, Wang F W and Wen G H 2001 J. Phys.: Condens. Matter 13 L747
[27]	Banerjee S K 1964 Phys. Lett. 12 16
[28]	Samanta T, Das I and Banerjee S 2007 Appl. Phys. Lett. 91 152506
[29]	Li L, Nishimura K, Huo D, Kadonaga M, Namiki T and Qian Z H 2011 Appl. Phys. Exp. 4 093101
[30]	Li L, Nishimura K, Usui G, Huo D and Qian Z H 2012 Intermetallics 23 101
[31]	Chen J, Shen B G, Dong Q Y and Sun J R 2010 Solid State Commun. 150 1429
[32]	Phan M H, Wood G T, Chaturvedi A, Stefanoski S, Nolas G S and Srikanth H 2008 Appl. Phys. Lett. 93 252505
[33]	Shen J, Zhao J L, Hu F X, Wu J F, Sun J R and Shen B G 2010 Chin. Phys. B 19 047502
[34]	Li L and Nishimura K 2009 Appl. Phys. Lett. 95 132505
[35]	Shen B G, Sun J R, Hu F X, Zhang H W and Chen Z H 2009 Adv. Mater. 21 4545

[1]	Magnetocaloric properties of phenolic resin bonded La(Fe,Si)₁₃-based plates and its use in a hybrid magnetic refrigerator Shao-Shan Xu(徐少山), Qi Fu(付琪), Yi-Fan Zhou(周益帆), Ling Peng(彭铃), Xin-Qiang Gao(高新强), Zhen-Xing Li(李振兴), Mao-Qiong Gong(公茂琼), Xue-Qiang Dong(董学强), and Jun Shen(沈俊). Chin. Phys. B, 2023, 32(2): 027502.
[2]	Giant low-field cryogenic magnetocaloric effect in polycrystalline LiErF₄ compound Zhaojun Mo(莫兆军), Jianjian Gong(巩建建), Huicai Xie(谢慧财), Lei Zhang(张磊), Qi Fu(付琪), Xinqiang Gao(高新强), Zhenxing Li(李振兴), and Jun Shen(沈俊). Chin. Phys. B, 2023, 32(2): 027503.
[3]	Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo₄O₇ Tina Raoufi, Jincheng He(何金城), Binbin Wang(王彬彬), Enke Liu(刘恩克), and Young Sun(孙阳). Chin. Phys. B, 2023, 32(1): 017504.
[4]	Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni₃₅Co₁₅Mn₃₃Fe₂Ti₁₅ alloy ribbons Yong Li(李勇), Liang Qin(覃亮), Hongguo Zhang(张红国), and Lingwei Li(李领伟). Chin. Phys. B, 2022, 31(8): 087103.
[5]	Large inverse and normal magnetocaloric effects in HoBi compound with nonhysteretic first-order phase transition Yan Zhang(张艳), You-Guo Shi(石友国), Li-Chen Wang(王利晨), Xin-Qi Zheng(郑新奇), Jun Liu(刘俊), Ya-Xu Jin(金亚旭), Ke-Wei Zhang(张克维), Hong-Xia Liu(刘虹霞), Shuo-Tong Zong(宗朔通), Zhi-Gang Sun(孙志刚), Ji-Fan Hu(胡季帆), Tong-Yun Tong(赵同云), and Bao-Gen Shen(沈保根). Chin. Phys. B, 2022, 31(7): 077501.
[6]	Magnetic and magnetocaloric effect in a stuffed honeycomb polycrystalline antiferromagnet GdInO₃ Yao-Dong Wu(吴耀东), Wei-Wei Duan(段薇薇), Qiu-Yue Li(李秋月), Yong-Liang Qin(秦永亮),Zhen-Fa Zi(訾振发), and Jin Tang(汤进). Chin. Phys. B, 2022, 31(6): 067501.
[7]	Magnetic properties and magnetocaloric effects of Tm_1-xEr_xCuAl (x = 0.25, 0.5, and 0.75) compounds Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Chin. Phys. B, 2022, 31(12): 127501.
[8]	Magnetic properties and magnetocaloric effect in RE₅₅Co₃₀Al₁₀Si₅ (RE = Er and Tm) amorphous ribbons Hao Sun(孙浩), Junfeng Wang(王俊峰), Lu Tian(田路), Jianjian Gong(巩建建), Zhaojun Mo(莫兆军), Jun Shen(沈俊), and Baogen Shen(沈保根). Chin. Phys. B, 2022, 31(11): 117503.
[9]	Magnetism and giant magnetocaloric effect in rare-earth-based compounds R₃BWO₉ (R = Gd, Dy, Ho) Lu-Ling Li(李炉领), Xiao-Yu Yue(岳小宇), Wen-Jing Zhang(张文静), Hu Bao(鲍虎), Dan-Dan Wu(吴丹丹), Hui Liang(梁慧), Yi-Yan Wang(王义炎), Yan Sun(孙燕), Qiu-Ju Li(李秋菊), and Xue-Feng Sun(孙学峰). Chin. Phys. B, 2021, 30(7): 077501.
[10]	Metamagnetic transition and reversible magnetocaloric effect in antiferromagnetic DyNiGa compound Yan-Hong Ding(丁燕红), Fan-Zhen Meng(孟凡振), Li-Chen Wang(王利晨), Ruo-Shui Liu(刘若水), Jun Shen(沈俊). Chin. Phys. B, 2020, 29(7): 077501.
[11]	Effect of Ni substitution on the formability and magnetic properties of Gd₅₀Co₅₀ amorphous alloy Ben-Zheng Tang(唐本镇), Xiao-Ping Liu(刘晓萍), Dong-Mei Li(李冬梅), Peng Yu(余鹏), Lei Xia(夏雷). Chin. Phys. B, 2020, 29(5): 056401.
[12]	Multicaloric and coupled-caloric effects Jia-Zheng Hao(郝嘉政), Feng-Xia Hu(胡凤霞), Zi-Bing Yu(尉紫冰), Fei-Ran Shen(沈斐然), Hou-Bo Zhou(周厚博), Yi-Hong Gao(高怡红), Kai-Ming Qiao(乔凯明), Jia Li(李佳), Cheng Zhang(张丞), Wen-Hui Liang(梁文会), Jing Wang(王晶), Jun He(何峻), Ji-Rong Sun(孙继荣), Bao-Gen Shen(沈保根). Chin. Phys. B, 2020, 29(4): 047504.
[13]	Magnetocaloric effect and critical behavior of the Mn-rich itinerant material Mn₃GaC with enhanced ferromagnetic interaction Pengfei Liu(刘鹏飞), Jie Peng(彭杰), Mianqi Xue(薛面起), Bosen Wang(王铂森). Chin. Phys. B, 2020, 29(4): 047503.
[14]	Giant low-field magnetocaloric effect in EuTi_1-xNb_xO₃ (x=0.05, 0.1, 0.15, and 0.2) compounds Wen-Hao Jiang(姜文昊), Zhao-Jun Mo(莫兆军), Jia-Wei Luo(罗佳薇), Zhe-Xuan Zheng(郑哲轩), Qiu-Jie Lu(卢秋杰), Guo-Dong Liu(刘国栋), Jun Shen(沈俊), Lan Li(李岚). Chin. Phys. B, 2020, 29(3): 037502.
[15]	Improvement of the low-field-induced magnetocaloric effect in EuTiO₃ compounds Shuang Zeng(曾爽), Wen-Hao Jiang(姜文昊), Hui Yang(杨慧), Zhao-Jun Mo(莫兆军) Jun Shen(沈俊), and Lan Li(李岚) . Chin. Phys. B, 2020, 29(12): 127501.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Magnetic properties and magnetocaloric effects in HoPd intermetallic

Cite this article:

Online attention