High-pressure synthesis, characterization, and equation of state of double perovskite Sr2CoFeO6

doi:10.1088/1674-1056/24/1/017503

Abstract Double perovskite oxide Sr₂CoFeO₆ (SCFO) has been obtained using a high-pressure and high-temperature (HPHT) synthesis method. Valence states of Fe and Co and their distributions in SCFO were examined with X-ray photoelectron spectroscopy. The electric transport behavior of SCFO showed a semiconductor behavior that can be well described by Mott's law for variable-range hopping conduction. The structural stability of SCFO was investigated at pressures up to 31 GPa with no pressure-induced phase transition found. Bulk modulus B₀ was determined to be 163(2) GPa by fitting the pressure-volume data to the Birch-Murnaghan equation of state.

Keywords: double perovskite oxide electric properties high pressure

Received: 19 July 2014
Revised: 22 September 2014
Accepted manuscript online:

PACS:	75.47.Lx	(Magnetic oxides)
	61.05.cp	(X-ray diffraction)
	64.60.-i	(General studies of phase transitions)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51172194 and 51172091), the Program for New Century Excellent Talents in University, China (Grant No. NCET-12-0240), and Jilin Province Science and Technology Development Program, China (Grant No. 20130101023JC).

Corresponding Authors: Wang Xin
E-mail: xin_wang@jlu.edu.cn

Cite this article:

Pan Yue-Wu (潘跃武), Zhu Pin-Wen (朱品文), Wang Xin (王欣) High-pressure synthesis, characterization, and equation of state of double perovskite Sr₂CoFeO₆ 2015 Chin. Phys. B 24 017503

[1]	Kobayashi K I, Kimura T, Sawada H, Terakura K and Tokura Y 1998 Nature 395 677
[2]	DeMarco M, Blackstead H A, Dow J D, Wu M K, Chen D Y, Chien F Z, Haka M, Toorongian S and Fridmann J 2000 Phys. Rev. B 62 14301
[3]	Kato H, Okuda T, Okimoto Y, Tomioka Y, Oikawa K, Kamiyama T and Tokura Y 2004 Phys. Rev. B 69 184412
[4]	Phatak R, Krishnan K, Sali S K, Das A and Nigam A K 2013 J. Magn. Magn. Mater. 344 129
[5]	Murthy J K and Venimadhav A 2013 J. Appl. Phys. 113 163906
[6]	Pradheesh R, Nair H S, Sankaranarayanan V and Sethupathi K 2012 Eur. Phys. J. B 85 260
[7]	Martinez-Lope M J, Alonso J A, Casais M T and Fernandez-Diaz M T 2002 Eur. J. Inorg. Chem. 9 2463
[8]	Rammeh N, Ehrenberg H, Fuess H and Cheikkh-Rouhou A 2006 Phys. Status Solidi C 3 3225
[9]	Hinatsu Y and Doi Y 2006 J. Solid State Chem. 179 2079
[10]	Pradheesh R, Nair H S, Kumar C M N, Lamsal J, Nirmala R, Santhosh P N, Yelon W B, Malik S K, Sankaranarayanan V and Sethupathi K 2012 J. Appl. Phys. 111 053905
[11]	Viola M C, Martínez-Lope M J, Alonso J A, Velasco P, Martínez J L, Pedregosa J C, Carbonio R E and Fernández-Díaz M T 2002 Chem. Mater. 14 812
[12]	Bezdicka P, Fournés L, Wattiaux A, Grenier J C and Pouchard M 1994 Solid State Commun. 91 501
[13]	Nomura K, Rykov A I, Nemudry A P and Mitsui T 2007 Thin Solid Films 515 8645
[14]	Bannikov V V, Shein I R, Kozhevnikov V L and Ivanovskii A L 2008 J. Struc. Chem. 49 781
[15]	Faik A, Gateshki M, Igartua J M, Pizarro J L, Insausti M, Kaindl R and Grzechnik A 2008 J. Solid State Chem. 181 1759
[16]	Augsburger M S, Viola M C, Pedregosa J C, Munoz A, Alonso J A and Carbonio R E 2005 J. Mater. Chem. 15 993
[17]	Ortega-San Martin L, Chapman J P, Lezama L, Sanchez-Marcos J, Rodriguez-Fernandez J, Isabel Arriortua M and Rojo T 2005 J. Mater. Chem. 15 183
[18]	Bull C L, Gleeson D and Knight K S 2003 J. Phys.: Condens. Matter 15 4927
[19]	Retuerto M, Martínez-Lope M J, García-Hernández M, Fernández-Díaz M T and Alonso J A 2008 Eur. J. Inorg. Chem. 4 588
[20]	Gateshki M, Igartua J M and Hernandez-Bocanegra E 2003 J. Phys.: Condens Matter 15 6199
[21]	Viola M C, Martinez-Lope M J, Alonso J A, Martinez J L, De Paoli J M, Pagola S, Pedregosa J C, Fernandez-Diaz M T and Carbonio R E 2003 Chem. Mater. 15 1655
[22]	Ivanov S A, Nordblad P, Mathieu R, Tellgren R and Ritter C 2010 Dalton Trans. 39 11136
[23]	Manoun B, Igartua J M, Gateshki M and Saxena S K 2008 J. Mol. Struct. 888 244
[24]	Lufaso M W, Gemmill W R, Mugavero S J Ⅲ, Lee Y, Vogt T and Loye H C 2006 J. Solid State Chem. 179 3556
[25]	Wu H P, Qian Y, Tan W S, Xiao C Y, Deng K M and Lu R F 2011 Appl. Phys. Lett. 99 123116
[26]	Yang Y, Jiang Y S, Wang Y W and Sun Y B 2007 J. Mol. Catal. A: Chem. 270 56
[27]	Wang P, Yao L, Wang M and Wu W 2000 J. Alloys Compd. 311 53
[28]	Viret M, Ranno L and Coey J M D 1997 Phys. Rev. B 55 8067
[29]	Coey J M D, Viret M and Ranno L 1995 Phys. Rev. Lett. 75 3910
[30]	De Teresa J M, Ibarra M R, Blasco J, Garcia J, Marquina C and Algarabel P A 1996 Phys. Rev. B 54 1187
[31]	Birch F 1947 Phys. Rev. 71 809

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High-pressure synthesis, characterization, and equation of state of double perovskite Sr2CoFeO6

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High-pressure synthesis, characterization, and equation of state of double perovskite Sr₂CoFeO₆