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Recension of boron nitride phase diagram based on high-pressure and high-temperature experiments |
| Ruike Zhang(张瑞柯)1, Ruiang Guo(郭睿昂)1, Qian Li(李倩)1, Shuaiqi Li(李帅琦)2, Haidong Long(龙海东)1, and Duanwei He(贺端威)1,3,† |
1 Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China;
2 College of Physics and Electronic Engineering, Chongqing Normal University, Chongqing 401331, China;
3 Key Laboratory of High Energy Density Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610065, China |
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Abstract Cubic boron nitride and hexagonal boron nitride are the two predominant crystalline structures of boron nitride. They can interconvert under varying pressure and temperature conditions. However, this transformation requires overcoming significant potential barriers in dynamics, which poses great difficulty in determining the c-BN/h-BN phase boundary. This study used high-pressure in situ differential thermal measurements to ascertain the temperature of h-BN/c-BN conversion within the commonly used pressure range (3-6 GPa) for the industrial synthesis of c-BN to constrain the $P$-$T$ phase boundary of h-BN/c-BN in the pressure-temperature range as much as possible. Based on the analysis of the experimental data, it is determined that the relationship between pressure and temperature conforms to the following equation: $P = a + \frac{1}{b}T$. Here, $P$ denotes the pressure (GPa) and $T$ is the temperature (K). The coefficients are $a = -3.8\pm0.8$ GPa and $b = 229.8\pm17.1$ GPa/K. These findings call into question existing high-pressure and high-temperature phase diagrams of boron nitride, which seem to overstate the phase boundary temperature between c-BN and h-BN. The BN phase diagram obtained from this study can provide critical temperature and pressure condition guidance for the industrial synthesis of c-BN, thus optimizing synthesis efficiency and product performance.
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Received: 14 February 2024
Revised: 16 July 2024
Accepted manuscript online: 01 August 2024
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PACS:
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81.30.-t
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(Phase diagrams and microstructures developed by solidification and solid-solid phase transformations)
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81.30.Dz
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(Phase diagrams of other materials)
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81.30.Hd
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(Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder)
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64.70.-p
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(Specific phase transitions)
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| Fund: Project supported by the National Key R&D Program of China (Grant No. 2023YFA1406200). |
Corresponding Authors:
Duanwei He
E-mail: duanweihe@scu.edu.cn
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Cite this article:
Ruike Zhang(张瑞柯), Ruiang Guo(郭睿昂), Qian Li(李倩), Shuaiqi Li(李帅琦), Haidong Long(龙海东), and Duanwei He(贺端威) Recension of boron nitride phase diagram based on high-pressure and high-temperature experiments 2024 Chin. Phys. B 33 108103
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