| CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
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Tuning the magnetocaloric and structural properties of La0.67Sr0.28Pr0.05Mn1-xCoxO3 refrigeration materials |
| Changji Xu(徐长吉)1, Xinyu Jiang(姜心雨)1, Zhengguang Zou(邹正光)1,2,†, Zhuojia Xie(谢卓家)1, Weijian Zhang(张伟建)1, and Min Feng(冯敏)1 |
1 College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China;
2 Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials, Guilin University of Technology, Guilin 541004, China |
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Abstract The structural, magnetic and magnetocaloric properties of perovskite manganites La$_{0.67}$Sr$_{0.28}$Pr$_{0.05}$Mn$_{1-x}$Co$_{x}$O$_{3}$ ($x = 0.05$, 0.075 and 0.10) (LSPMCO) are investigated. LSPMCO crystallizes as a rhombohedral structure with $R$-$3c$ space group. As the Co content increases, the cell volume expands, the Mn-O-Mn bond angle reduces and the length of the Mn-O bond increases. The samples show irregular submicron particles under a Zeiss scanning electron microscopy. The particle size becomes larger with increasing doping. The chemical composition of the samples is confirmed by x-ray photoelectron spectroscopy (XPS). The ferromagnetic (FM) to paramagnetic (PM) phase transition occurs near the Curie temperature ($T_{\rm C}$), and all transitions are second-order phase transitions (SMOPT) characterized by minimal thermal and magnetic hystereses. Critical behavior analysis indicates that the critical parameters of LSPMCO closely align with those predicted by the mean-field model. The $T_{\rm C}$ declines with Co doping and reaches near room temperature (302 K) at $x = 0.075$. The maximum magnetic entropy change ($-\Delta S_{\rm M}^{\max}$) at $x = 0.05$ is 4.27 J/kg$\cdot$K, and the relative cooling power (RCP) peaks at 310.81 J/K. Therefore, the system holds significant potential for development as a magnetic refrigeration material, meriting further professional and objective evaluation.
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Received: 21 June 2024
Revised: 10 September 2024
Accepted manuscript online: 10 October 2024
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PACS:
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75.30.Sg
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(Magnetocaloric effect, magnetic cooling)
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75.30.-m
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(Intrinsic properties of magnetically ordered materials)
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75.47.Lx
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(Magnetic oxides)
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75.10.-b
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(General theory and models of magnetic ordering)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant No. 52162038). |
Corresponding Authors:
Zhengguang Zou
E-mail: zouzgglut@163.com
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Cite this article:
Changji Xu(徐长吉), Xinyu Jiang(姜心雨), Zhengguang Zou(邹正光), Zhuojia Xie(谢卓家), Weijian Zhang(张伟建), and Min Feng(冯敏) Tuning the magnetocaloric and structural properties of La0.67Sr0.28Pr0.05Mn1-xCoxO3 refrigeration materials 2024 Chin. Phys. B 33 127501
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