Structure, magnetism and magnetocaloric effects in Er5Si3Bx (x=0.3, 0.6) compounds

doi:10.1088/1674-1056/ace684

Abstract We investigate the structure, magnetic properties, magnetic phase transitions and magnetocaloric effects (MCEs) of Er₅Si₃B_x (x=0.3, 0.6) compounds. The Er₅Si₃B_x (x=0.3, 0.6) compounds crystalize in a Mn₅Si₃ type hexagonal structure (space group: P63/cm) and exhibit a successive complicated magnetic phase transition. The extensive magnetic phase transitions contribute to the broad temperature range of MCEs exhibiting in Er₅Si₃B_x (x=0.3, 0.6) compounds, with maximum magnetic entropy change (-ΔS_M^max) and refrigeration capacity of 10.2 J·kg^-1·K^-1, 356.3 J/kg and 11.5 J·kg^-1·K^-1, 393.3 J/kg under varying magnetic fields 0-5 T, respectively. Remarkably, the δT_FWHM values (the temperature range corresponding to 1/2×|-ΔS_M^max|) of Er₅Si₃B_x (x=0.3, 0.6) compounds were up to 41.8 K and 39.6 K, respectively. Thus, the present work provides a potential magnetic refrigeration material with a broad temperature range MCEs for applications in cryogenic magnetic refrigerators.

Keywords: magnetic materials cryogenic magnetic refrigeration magnetic phase transition magnetocaloric effects

Received: 26 May 2023
Revised: 03 July 2023
Accepted manuscript online: 12 July 2023

PACS:	75.30.Sg	(Magnetocaloric effect, magnetic cooling)
	75.47.Np	(Metals and alloys)

Fund: This work was supported by Science and Technology Research Project for Education Department of Jiangxi Province, China (Grant No. GJJ218509).

Corresponding Authors: Zhihong Hao
E-mail: love_hzh@126.com

Cite this article:

Zhihong Hao(郝志红), Hui Liu(刘辉), and Juguo Zhang(张聚国) Structure, magnetism and magnetocaloric effects in Er₅Si₃B_x (x=0.3, 0.6) compounds 2023 Chin. Phys. B 32 117501

[1] Cheng W, Ding D and Lei X 2016 Chin. Phys. Lett. 33 16102
[2] Hu F, Zhang G Y, Huang Y J, et al. 2014 Chin. Phys. Lett. 31 057501
[3] Yu X Y, Feng H L, Gu X, et al. 2019 Acta Phys. Sin. 68 247201 (in Chinese)
[4] Li G Q, Ke Y J, Zhang H B, et al. 2019 Acta Phys. Sin. 68 217501 (in Chinese)
[5] Cao Y Z and Zhao Y 2019 Acta Phys. Sin. 68 168502 (in Chinese)
[6] Chen X and Zhang M H 2018 Acta Phys. Sin. 67 197501 (in Chinese)
[7] Tang B Z, Liu X P, Li D M, Yu P and Xia L 2020 Chin. Phys. B 29 056401
[8] Ma Y F, Tang B Z, Xia L and Ding D 2016 Chin. Phys. B 33 126101
[9] Bao L F, Huang W D and Ren Y J 2016 Chin. Phys. Lett. 33 77502
[10] Tian L, Gong J J, Fu Q, Gao X Q, Mo Z J, Li Z X and Shen J 2023 J. Magn. Magn. Mater. 566 170194
[11] Tian L, Fu Q, Mo Z J, Sun H, Li Z X, Shen J and Liu G D 2023 J. Magn. Magn. Mater. 576 170770
[12] Cheng J H, Wang Y G and Xie D 2015 Chin. Phys. Lett. 32 17503
[13] Ding D, Zhang Y Q and Xia L 2015 Chin. Phys. Lett. 32 106101
[14] Mo Z J, Shen J, Yan L Q, Tang C C, Lin J, Wu J F, Sun J R, Wang L C, Zheng X Q and Shen B G 2013 Appl. Phys. Lett. 103 052409
[15] Ding D, Wang P, Guan Q, et al. 2013 Chin. Phys. Lett. 30 096104
[16] Hao Z H, Wang H Y, Zhang Q, et al. 2018 Acta Phys. Sin. 67 247502 (in Chinese)
[17] Zhang H, Xing C F, Long K W, et al. 2018 Acta Phys. Sin. 67 207501 (in Chinese)
[18] Yang J J, Zhao J L, Xu L, et al. 2018 Acta Phys. Sin. 67 077501 (in Chinese)
[19] Guo D, Zhang Y K, Wang Y M, et al. 2020 Chin. Phys. B 29 107502
[20] Ding Y H, Meng F Z and Wang L C 2020 Chin. Phys. B 29 077501
[21] Hao J Z, Hu F X, Yu Z B, et al. 2020 Chin. Phys. B 29 047504
[22] Liu P F, Peng J, Xue M Q, et al. 2020 Chin. Phys. B 29 047503
[23] Jiang W H, Mo Z J and Luo J W 2020 Chin. Phys. B 29 037502
[24] Yu T L, Yu X Y, Yang E, et al. 2019 Chin. Phys. B 28 067501
[25] Yao G Q, Sun S Y, Yang J C, Wu H F, Wang Q, Zhu J and Cui W B 2021 Scr. Mater. 194 113649
[26] Takeya H, Pecharsky V K, Gschneidner K A and Moorman J O 1994 Appl. Phys. Lett. 64 2739
[27] Zhang Y K, Xu P, Zhu J, Yan S M, Zhang J C and Li L W 2023 Mater. Today Phys. 32 101031
[28] Sun H, Wang J F, Tian L, Gong J J, Mo Z J, Shen J and Shen B G 2022 Chin. Phys. B 31 117503
[29] Zhang Y K, Guo D, Li H D, Geng S H, Wang J, Li X, Xu H, Ren Z M and Wilde G 2018 J. Alloys Compd. 733 40
[30] Feng J Q, Liu Y H, Sui J H, He A N, Xia W X, Wang W H and Wang J Q 2021 Mater. Today Phys. 21 100528
[31] Li L W, Yuan Y, Qi Y, Wang Q and Zhou S Q 2017 Mater. Res. Lett. 6 67
[32] Balfour E A, Shang Y F, Zheng Q, Cao Y T, Fu H, E-Gendy A A and Hadimani R L 2018 J. Magn. Magn. Mater. 467 108
[33] Zhang H, Xu Z Y, Zheng X Q, Shen J, Hu F X, Sun J R and Shen B G 2012 Solid State Commun. 152 1127
[34] Semitelou I P, Yakinthos J K and Roudaut E 1995 J. Phys. Chem. Solids 56 891
[35] Roger J, Yahia M B, Babizhetskyy V, Bauer J, Cordier S, Guerin R, Hiebl K, Rocquefelte X, Saillard J Y and Halet J F 2006 J. Solid State Chem. 179 2310
[36] Mohapatra N, Mukherjee K, Iyer K K and Sampathkumaran E V 2011 J. Phys.:Condens. Matter 23 496001
[37] Zhang H, Wu Y Y, Long Y, Wang H S, Zhong K X, Hu F X, Sun J R and Shen B G 2014 J. Appl. Phys. 116 213902
[38] Hermes W, Rodewakd U C and Pottgen R J Appl. Phys. 108 113919
[39] Li D X, Yamamura T, Nimori S, Homma Y and Honda F 2013 Appl. Phys. Lett. 102 152409
[40] Fukuma H, Suzuki T and Kasuya T 1985 J. Magn. Magn. Mater. 52 7
[41] Banerjee B K 1964 Phys. Lett. 12 16
[42] Franco V, Blázquez J S and Upus J J 2018 Prog. Mater. Sci. 93 112
[43] Gschneidner K A and Pecharsky V K 2000 Annu. Rev. Mater. Sci. 30 387
[44] Griffith L D, Mudryk Y, Slaughter J and Pecharsky V K J Appl. Phys. 123 034902

[1]	Magnetic and electronic properties of La-doped hexagonal 4H-SrMnO₃ Jie Li(李杰), Yinan Chen(陈一楠), Nuo Gong(宫诺), Xin Huang(黄欣), Zhihong Yang(杨志红), and Yakui Weng(翁亚奎). Chin. Phys. B, 2024, 33(1): 017502.
[2]	Magnetic van der Waals materials: Synthesis, structure, magnetism, and their potential applications Zhongchong Lin(林中冲), Yuxuan Peng(彭宇轩), Baochun Wu(吴葆春), Changsheng Wang(王常生), Zhaochu Luo(罗昭初), and Jinbo Yang(杨金波). Chin. Phys. B, 2022, 31(8): 087506.
[3]	Magnetic and magnetocaloric effect in a stuffed honeycomb polycrystalline antiferromagnet GdInO₃ Yao-Dong Wu(吴耀东), Wei-Wei Duan(段薇薇), Qiu-Yue Li(李秋月), Yong-Liang Qin(秦永亮),Zhen-Fa Zi(訾振发), and Jin Tang(汤进). Chin. Phys. B, 2022, 31(6): 067501.
[4]	Raman spectroscopy investigation on the pressure-induced structural and magnetic phase transition in two-dimensional antiferromagnet FePS₃ Hong Zeng(曾鸿), Tingting Ye(叶婷婷), Peng Cheng(程鹏), Deyuan Yao(姚德元), and Junfeng Ding(丁俊峰). Chin. Phys. B, 2022, 31(5): 056109.
[5]	Formation of L1₀-FeNi hard magnetic material from FeNi-based amorphous alloys Yaocen Wang(汪姚岑), Ziyan Hao(郝梓焱), Yan Zhang(张岩), Xiaoyu Liang(梁晓宇), Xiaojun Bai(白晓军), and Chongde Cao(曹崇德). Chin. Phys. B, 2022, 31(4): 046301.
[6]	CeAu₂In₄: A candidate of quasi-one-dimensional antiferromagnetic Kondo lattice Meng Lyu(吕孟), Hengcan Zhao(赵恒灿), Jiahao Zhang(张佳浩), Zhen Wang(王振), Shuai Zhang(张帅), and Peijie Sun(孙培杰). Chin. Phys. B, 2021, 30(8): 087101.
[7]	Oxygen vacancy control of electrical, optical, and magnetic properties of Fe_0.05Ti_0.95O₂ epitaxial films Qing-Tao Xia(夏清涛), Zhao-Hui Li(李召辉), Le-Qing Zhang(张乐清), Feng-Ling Zhang(张凤玲), Xiang-Kun Li(李祥琨), Heng-Jun Liu(刘恒均), Fang-Chao Gu(顾方超), Tao Zhang(张涛), Qiang Li(李强), and Qing-Hao Li(李庆浩). Chin. Phys. B, 2021, 30(11): 117701.
[8]	Mn-based permanent magnets Jinbo Yang(杨金波), Wenyun Yang(杨文云), Zhuyin Shao(邵珠印), Dong Liang(梁栋), Hui Zhao(赵辉), Yuanhua Xia(夏元华), Yunbo Yang(杨云波). Chin. Phys. B, 2018, 27(11): 117503.
[9]	Serrated magnetic properties in metallic glass by thermal cycle Myong-Chol Ri(李明哲), Sajad Sohrabi, Da-Wei Ding(丁大伟), Bang-Shao Dong(董帮少), Shao-Xiong Zhou(周少雄), Wei-Hua Wang(汪卫华). Chin. Phys. B, 2017, 26(6): 066101.
[10]	Structure dependence of magnetic properties in yttrium iron garnet by metal-organic decomposition method Yuan Liu(刘园), Xiang Wang(王翔), Jie Zhu(朱杰), Runsheng Huang(黄润生), Dongming Tang(唐东明). Chin. Phys. B, 2017, 26(5): 057501.
[11]	Pressure induced magnetic and semiconductor-metal phase transitions in Cr₂MoO₆ San-Dong Guo(郭三栋). Chin. Phys. B, 2016, 25(5): 057104.
[12]	Effects of Mg substitution on the structural and magnetic properties of Co_0.5Ni_0.5-xMg_xFe₂O₄ nanoparticle ferrites R M Rosnan, Z Othaman, R Hussin, Ali A Ati, Alireza Samavati, Shadab Dabagh, Samad Zare. Chin. Phys. B, 2016, 25(4): 047501.
[13]	Review of magnetic properties and magnetocaloric effect in the intermetallic compounds of rare earth with low boiling point metals Ling-Wei Li(李领伟). Chin. Phys. B, 2016, 25(3): 037502.
[14]	Magnetocaloric effect study of SrFe_0.8Co_0.2O₃ single crystal prepared under high pressure Xia Hai-Liang (夏海亮), Qin Xiao-Mei (秦晓梅), Yang Jun-Ye (杨俊叶), Yin Yun-Yu (殷云宇), Dai Jian-Hong (戴建洪), Shi Wang-Zhou (石旺舟), Long You-Wen (龙有文). Chin. Phys. B, 2015, 24(5): 050701.
[15]	Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals Chen Li-Min (陈丽敏), Guo Ying (郭颖), Liu Xu-Guang (刘旭光), Xie Qi-Yun (解其云), Tao Zhi-Kuo (陶志阔), Chen Jing (谌静), Zhou Ling-Ling (周玲玲), Liu Chun-Sheng (刘春生). Chin. Phys. B, 2015, 24(12): 127503.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Structure, magnetism and magnetocaloric effects in Er5Si3Bx (x=0.3, 0.6) compounds

Cite this article:

Online attention

Structure, magnetism and magnetocaloric effects in Er₅Si₃B_x (x=0.3, 0.6) compounds