1 Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China; 2 University of Science and Technology of China, Hefei 230026, China; 3 School of Physics and Electronics, Central South University, Changsha 410083, China; 4 State Key Laboratory for Mesoscopic Physics, Collaborative Innovation Center of Quantum Matter, School of Physics, Peking University, Beijing 100871, China; 5 Beijing Academy of Quantum Information Sciences, Beijing 100085, China
Abstract High-quality large 1 phase of Ti (, Se, and S) single crystals have been grown by chemical vapor transport using iodine as a transport agent. The samples are characterized by compositional and structural analyses, and their properties are investigated by Raman spectroscopy. Several phonon modes have been observed, including the widely reported and modes, the rarely reported mode (183 cm for TiTe, and 185 cm for TiS), and even the unexpected mode (85 cm) of TiTe. Most phonons harden with the decrease of temperature, except that the mode of TiTe and the and "/Sh" modes of TiS soften with the decrease of temperature. In addition, we also found phonon changes in TiSe that may be related to charge density wave phase transition. Our results on Ti phonons will help to understand their charge density wave and superconductivity.
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 12074436 and U1930116) and the Innovation-driven Plan in Central South University (Grant No. 2016CXS032).
Xiao-Fang Tang(唐筱芳), Shuang-Xing Zhu(朱双兴), Hao Liu(刘豪), Chen Zhang(章晨), Qi-Yi Wu(吴旗仪), Zi-Teng Liu(刘子腾), Jiao-Jiao Song(宋姣姣), Xiao Guo(郭晓), Yong-Song Wang(王永松), He Ma(马赫), Yin-Zou Zhao(赵尹陬), Fan-Ying Wu(邬钒颖), Shu-Yu Liu(刘姝妤), Kai-Hui Liu(刘开辉), Ya-Hua Yuan(袁亚华), Han Huang(黄寒), Jun He(何军), Wen Xu(徐文), Hai-Yun Liu(刘海云), Yu-Xia Duan(段玉霞), and Jian-Qiao Meng(孟建桥) Growth, characterization, and Raman spectra of the 1T phases of TiTe2, TiSe2, and TiS2 2022 Chin. Phys. B 31 037103
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