Magnetostructural transformation and magnetocaloric effect in Mn48-xVxNi42Sn10 ferromagnetic shape memory alloys

doi:10.1088/1674-1056/27/3/037504

Abstract In this work, we tuned the magnetostructural transformation and the coupled magnetocaloric properties of Mn_48-xV_xNi₄₂Sn₁₀ (x=0, 1, 2, and 3) ferromagnetic shape memory alloys prepared by means of partial replacement of Mn by V. It is observed that the martensitic transformation temperatures decrease with the increase of V content. The shift of the transition temperatures to lower temperatures driven by the applied field, the metamagnetic behavior, and the thermal hysteresis indicates the first-order nature for the magnetostructural transformation. The entropy changes with a magnetic field variation of 0-5 T are 15.2, 18.8, and 24.3 J·kg^-1·K^-1 for the x=0, 1, and 2 samples, respectively. The tunable martensitic transformation temperature, enhanced field driving capacity, and large entropy change suggest that Mn_48-xV_xNi₄₂Sn₁₀ alloys have a potential for applications in magnetic cooling refrigeration.

Keywords: magnetostructural coupling field driving capacity refrigeration capacity magnetocaloric effect

Received: 29 October 2017
Revised: 19 December 2017
Accepted manuscript online:

PACS:

75.30.Sg

(Magnetocaloric effect, magnetic cooling)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51601092, 51571121, and 11604148), the Fundamental Research Funds for the Central Universities, China (Grant Nos. 30916011344 and 30916011345), the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province, China, the Postdoctoral Science Foundation Funded Project (Grant No. 2016M591851), the Natural Science Foundation of Jiangsu Province, China (Grant Nos. BK20160833, 20160829, and 20140035), the Qing Lan Project of Jiangsu Province, the Priority Academic Program Development of Jiangsu Higher Education Institutions, and Shanxi Scholarship Council of China (Grant No. 2016-092).

Corresponding Authors: Feng Xu
E-mail: xufeng@njust.edu.cn

Cite this article:

Najam ul Hassan, Ishfaq Ahmad Shah, Tahira Khan, Jun Liu(刘俊), Yuanyuan Gong(龚元元), Xuefei Miao(缪雪飞), Feng Xu(徐锋) Magnetostructural transformation and magnetocaloric effect in Mn_48-xV_xNi₄₂Sn₁₀ ferromagnetic shape memory alloys 2018 Chin. Phys. B 27 037504

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Magnetostructural transformation and magnetocaloric effect in Mn48-xVxNi42Sn10 ferromagnetic shape memory alloys

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Magnetostructural transformation and magnetocaloric effect in Mn_48-xV_xNi₄₂Sn₁₀ ferromagnetic shape memory alloys