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Spectral investigation of R, Ce:YAG (R: Pr3+, Eu3+, Gd3+) single crystals and their applications in white LEDs |
Du Yong (杜勇)a, Shao Chong-Yun (邵冲云)a, Dong Yong-Jun (董永军)b, Yang Qiu-Hong (杨秋红)a, Hua Wei (华伟)b |
a School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China; b Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China |
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Abstract Eu3+, Pr3+, or Gd3+ codoped Ce:YAG single crystals were grown by using the Czochralski method. The photoluminescence (PL) emission and excitation spectra and transmittance were measured and investigated. The additional red-emitting bands were observed in the PL emission spectra of Eu,Ce:YAG and Pr,Ce:YAG single crystals and the formation of noticeable peaks was studied with reference to the schematic energy level diagrams. A red-shifted phenomenon was observed in the PL emission spectrum of Gd,Ce:YAG. With codoped Eu3+, Pr3+, or Gd3+ ions, warmer white light was achieved for the white light emitting diodes and the color rendering index became higher.
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Received: 22 April 2015
Revised: 05 June 2015
Accepted manuscript online:
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PACS:
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78.55.-m
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(Photoluminescence, properties and materials)
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85.60.Jb
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(Light-emitting devices)
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78.60.Fi
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(Electroluminescence)
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Corresponding Authors:
Dong Yong-Jun
E-mail: dongyj@siom.ac.cn
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Cite this article:
Du Yong (杜勇), Shao Chong-Yun (邵冲云), Dong Yong-Jun (董永军), Yang Qiu-Hong (杨秋红), Hua Wei (华伟) Spectral investigation of R, Ce:YAG (R: Pr3+, Eu3+, Gd3+) single crystals and their applications in white LEDs 2015 Chin. Phys. B 24 117801
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