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Chin. Phys. B, 2015, Vol. 24(11): 117801    DOI: 10.1088/1674-1056/24/11/117801
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Spectral investigation of R, Ce:YAG (R: Pr3+, Eu3+, Gd3+) single crystals and their applications in white LEDs

Du Yong (杜勇)a, Shao Chong-Yun (邵冲云)a, Dong Yong-Jun (董永军)b, Yang Qiu-Hong (杨秋红)a, Hua Wei (华伟)b
a School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China;
b Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
Abstract  Eu3+, Pr3+, or Gd3+ codoped Ce:YAG single crystals were grown by using the Czochralski method. The photoluminescence (PL) emission and excitation spectra and transmittance were measured and investigated. The additional red-emitting bands were observed in the PL emission spectra of Eu,Ce:YAG and Pr,Ce:YAG single crystals and the formation of noticeable peaks was studied with reference to the schematic energy level diagrams. A red-shifted phenomenon was observed in the PL emission spectrum of Gd,Ce:YAG. With codoped Eu3+, Pr3+, or Gd3+ ions, warmer white light was achieved for the white light emitting diodes and the color rendering index became higher.
Keywords:  photoluminescence      light-emitting device      electroluminescence  
Received:  22 April 2015      Revised:  05 June 2015      Accepted manuscript online: 
PACS:  78.55.-m (Photoluminescence, properties and materials)  
  85.60.Jb (Light-emitting devices)  
  78.60.Fi (Electroluminescence)  
Corresponding Authors:  Dong Yong-Jun     E-mail:  dongyj@siom.ac.cn

Cite this article: 

Du Yong (杜勇), Shao Chong-Yun (邵冲云), Dong Yong-Jun (董永军), Yang Qiu-Hong (杨秋红), Hua Wei (华伟) Spectral investigation of R, Ce:YAG (R: Pr3+, Eu3+, Gd3+) single crystals and their applications in white LEDs 2015 Chin. Phys. B 24 117801

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