Interfacial nanobubbles produced by long-time preserved cold water

doi:10.1088/1674-1056/26/10/106803

Abstract

Interfacial gaseous nanobubbles which have remarkable properties such as unexpectedly long lifetime and significant potential applications, are drawing more and more attention. However, the recent dispute about the contamination or gas inside the nanobubbles causes a large confusion due to the lack of simple and clean method to produce gas nanobubbles. Here we report a convenient and clean method to effectively produce interfacial nanobubbles based on a pure water system. By adding the cold water cooled at 4 ℃ for more than 48 h onto highly oriented pyrolytic graphite (HOPG) surface, we find that the average density and total volume of nanobubbles are increased to a high level and mainly dominated by the concentrations of the dissolved gases in cold water. Our findings and methods are crucial and helpful for settling the newly arisen debates on gas nanobubbles.

Keywords: nanobubbles atomic force microscopy gas saturation solubility

Received: 01 June 2017
Revised: 25 July 2017
Accepted manuscript online:

PACS:	68.08.-p	(Liquid-solid interfaces)
	81.07.-b	(Nanoscale materials and structures: fabrication and characterization)
	68.37.Ps	(Atomic force microscopy (AFM))
	64.75.Bc	(Solubility)

Fund:

Project supported by the Key Laboratory of Interfacial Physics and Technology, Chinese Academy of Sciences, the Open Research Project of the Large Scientific Facility of the Chinese Academy of Sciences, the National Natural Science Foundation of China (Grant Nos. 11079050, 11290165, 11305252, 11575281, and U1532260), the National Key Basic Research Program of China (Grant Nos. 2012CB825705 and 2013CB932801), the National Natural Science Foundation for Outstanding Young Scientists, China (Grant No. 11225527), the Shanghai Academic Leadership Program, China (Grant No. 13XD1404400), and the Program of the Chinese Academy of Sciences (Grant Nos. KJCX2-EW-W09 and QYZDJ-SSW-SLH019).

Corresponding Authors: Li-Juan Zhang, Li-Juan Zhang
E-mail: zhanglijuan@sinap.ac.cn;hujun@sinap.ac.cn

Cite this article:

Li-Min Zhou(周利民), Shuo Wang(王硕), Jie Qiu(邱杰), Lei Wang(王磊), Xing-Ya Wang(王兴亚), Bin Li(李宾), Li-Juan Zhang(张立娟), Jun Hu(胡钧) Interfacial nanobubbles produced by long-time preserved cold water 2017 Chin. Phys. B 26 106803

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Interfacial nanobubbles produced by long-time preserved cold water

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