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Entropy dominated behaviors of confined polymer-nanoparticle composites |
Cao Xue-Zheng (曹学正)a, Merlitz Holgera b, Sommer Jens-Uweb, Wu Chen-Xu (吴晨旭 )a |
a Department of Physics and ITPA, Xiamen University, Xiamen 361005, China; b Leibniz-Institut für Polymerforschung Dresden, Dresden 01069, Germany |
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Abstract The stretched polymers would lose their possible configurations if they are mixed with nanoparticles or touch on a hard wall, which leads to a strong depletion attraction responsible for the enrichment of nanoparticles near substrates. Moreover, it is found that there exists a sacrifice mechanism in confined pure polymer samples or polymer-nanoparticle mixtures that part of polymers in order to reach a minimum free energy for the total system, are adsorbed on hard walls even by losing their conformation. The understanding based on the current study provides a simple yet effective approach for the design of thin polymer composites.
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Received: 19 June 2012
Revised: 20 July 2012
Accepted manuscript online:
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PACS:
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82.35.Np
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(Nanoparticles in polymers)
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34.20.Gj
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(Intermolecular and atom-molecule potentials and forces)
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36.20.Ey
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(Conformation (statistics and dynamics))
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Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 10974162 and 11074208). |
Corresponding Authors:
Wu Chen-Xu
E-mail: cxwu@xmu.edu.cn
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Cite this article:
Cao Xue-Zheng (曹学正), Merlitz Holger, Sommer Jens-Uwe, Wu Chen-Xu (吴晨旭 ) Entropy dominated behaviors of confined polymer-nanoparticle composites 2012 Chin. Phys. B 21 118202
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