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Chin. Phys. B, 2008, Vol. 17(6): 2240-2244    DOI: 10.1088/1674-1056/17/6/050
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Preparation of p-type ZnO:(Al, N) by a combination of sol--gel and ion-implantation techniques

Xue Shu-Wen(薛书文)a)b), Zu Xiao-Tao(祖小涛)a), Shao Le-Xi(邵乐喜)b), Yuan Zhao-Lin(袁兆林)a), Xiang Xia(向霞)a), and Deng Hong(邓宏)c)
a Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, China; b Department of Physics, Zhanjiang Normal College, Zhanjiang 524048, China; c School of Microelectronics and Solid-state Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China
Abstract  We report the preparation of p-type ZnO thin films on (0001) sapphire substrates by a combination of sol--gel and ion-implantation techniques. The results of the Hall-effect measurements carried out at room temperature indicate that the N-implanted ZnO:Al films annealed at 600℃ have converted to p-type conduction with a hole concentration of 1.6$\times$1018cm-3, a hole mobility of 3.67cm2/V$\cdot$s and a minimum resistivity of 4.80cm$\cdot\Omega$. Ion-beam induced damage recovery has been investigated by x-ray diffraction (XRD), photoluminescence (PL) and optical transmittance measurements. Results show that diffraction peaks and PL intensities are decreased by N ion implantation, but they nearly recover after annealing at 600℃. Our results demonstrate a promising approach to fabricate p-type ZnO at a low cost.
Keywords:  ZnO      ion implantation      XRD  
Received:  22 October 2007      Revised:  10 December 2007      Accepted manuscript online: 
PACS:  81.15.-z (Methods of deposition of films and coatings; film growth and epitaxy)  
  73.50.Dn (Low-field transport and mobility; piezoresistance)  
  73.50.Jt (Galvanomagnetic and other magnetotransport effects)  
  73.61.Ga (II-VI semiconductors)  
  78.55.Et (II-VI semiconductors)  
  81.20.Fw (Sol-gel processing, precipitation)  
Fund: Project supported by the Program for New Century Excellent Talents in University (Grant No NCET-04-0899) and Special Foundation for University Subject Construction, Department of Education of Guangdong Province, China (Grant No [2006] 11).

Cite this article: 

Xue Shu-Wen(薛书文), Zu Xiao-Tao(祖小涛), Shao Le-Xi(邵乐喜), Yuan Zhao-Lin(袁兆林), Xiang Xia(向霞), and Deng Hong(邓宏) Preparation of p-type ZnO:(Al, N) by a combination of sol--gel and ion-implantation techniques 2008 Chin. Phys. B 17 2240

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