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Chin. Phys. B, 2016, Vol. 25(12): 128202    DOI: 10.1088/1674-1056/25/12/128202
INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Can secondary nucleation exist in ice banding of freezing colloidal suspensions?

Jia-Xue You(游家学)1, Jin-Cheng Wang(王锦程)1, Li-Lin Wang(王理林)2, Zhi-Jun Wang(王志军)1, Jun-Jie Li(李俊杰)1, Xin Lin(林鑫)1
1. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China;
2. School of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, China
Abstract  

The formation mechanism of ice banding in the system of freezing colloidal suspensions, which is of significance in frost heaving, ice-templating porous materials and biological materials, is still a mystery. Recently, the theory of secondary nucleation and growth of ice has been proposed to explain the emergence of a new ice lens. However, this theory has not been quantitatively examined. Here, we quantitatively measure the initial interfacial undercooling of a new ice lens and the nucleation undercoolings of suspensions. We find that the interfacial undercooling cannot satisfy the nucleation undercooling of ice and hence disprove the secondary nucleation mechanism for ice banding.

Keywords:  colloidal suspensions      freezing      nucleation      ice banding  
Received:  23 May 2016      Revised:  17 August 2016      Accepted manuscript online: 
PACS:  82.70.Dd (Colloids)  
  81.30.Fb (Solidification)  
  47.20.Hw (Morphological instability; phase changes)  
  02.60.Cb (Numerical simulation; solution of equations)  
Fund: 

Project supported by the National Natural Science Foundation of China (Grant Nos. 51371151 and 51571165), the Free Research Fund of State Key Laboratory of Solidification Processing, China (Grant No. 100-QP-2014), the Fund of State Key Laboratory of Solidification Processing in Northwestern Polytechnical University (NWPU), China (Grant No. 13-BZ-2014), and the Fundamental Research Funds for the Central Universities, China (Grant No. 3102015ZY020).

Corresponding Authors:  Zhi-Jun Wang, Xin Lin     E-mail:  zhjwang@nwpu.edu.cn;xlin@nwpu.edu.cn

Cite this article: 

Jia-Xue You(游家学), Jin-Cheng Wang(王锦程), Li-Lin Wang(王理林), Zhi-Jun Wang(王志军), Jun-Jie Li(李俊杰), Xin Lin(林鑫) Can secondary nucleation exist in ice banding of freezing colloidal suspensions? 2016 Chin. Phys. B 25 128202

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