Pressure-induced phase transitions in single-crystalline Cu4Bi4S9 nanoribbons

doi:10.1088/1674-1056/22/11/116201

Abstract In situ angle dispersive synchrotron X-ray diffraction and Raman scattering measurements under pressure are employed to study the structural evolution of Cu₄Bi₄S₉ nanoribbons, which are fabricated by using a facile solvothermal method. Both experiments show that a structural phase transition occurs near 14.5 GPa, and there is a pressure-induced reversible amorphization at about 25.6 GPa. The electrical transport property of a single Cu₄Bi₄S₉ nanoribbon under different pressures is also investigated.

Keywords: Cu₄Bi₄S₉ nanoribbon high pressure amorphization phase transition

Received: 13 May 2013
Revised: 08 June 2013
Accepted manuscript online:

PACS:	62.50.-p	(High-pressure effects in solids and liquids)
	61.05.cp	(X-ray diffraction)
	78.30.-j	(Infrared and Raman spectra)
	64.70.K-

Fund: Project supported by the National Basic Research Program of China (Grant No. 2012CB932302) and the National Natural Science Foundation of China (Grant No. 11174336).

Corresponding Authors: Yu Ri-Cheng
E-mail: rcyu@aphy.iphy.ac.cn

Cite this article:

Hu Jing-Yu (胡靖宇), Li Jing (李劲), Zhang Si-Jia (张思佳), Zhao Hao-Fei (赵豪飞), Zhang Qing-Hua (张庆华), Yao Yuan (姚湲), Zhao Qing (赵清), Shi Li-Jie (石丽洁), Zou Bing-Suo (邹炳锁), Li Yan-Chun (李延春), Li Xiao-Dong (李晓东), Liu Jing (刘景), Zhu Ke (朱恪), Liu Yu-Long (刘玉龙), Jin Chang-Qing (靳常青), Yu Ri-Cheng (禹日成) Pressure-induced phase transitions in single-crystalline Cu₄Bi₄S₉ nanoribbons 2013 Chin. Phys. B 22 116201

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Pressure-induced phase transitions in single-crystalline Cu4Bi4S9 nanoribbons

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Pressure-induced phase transitions in single-crystalline Cu₄Bi₄S₉ nanoribbons