a College of Information Engineering, China Jiliang University, Hangzhou 310018, China; b Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, Chinac Graduate School of Chinese Academy of Sciences, Beijing 100039, China
Abstract The upconversion properties of Er3+-doped heavy metal oxyfluoride germanate glasses under 975 nm excitation have been investigated. The intense green (551 and 529 nm) and relatively weak red (657 nm) emissions corresponding to the transitions 4S3/2 $\to$ 4I15/2,2H11/2 $\to$ 4I15/2 and 4F9/2 $\to$ 4I15/2, respectively, were simultaneously observed at room temperature. The content of PbF2 has an important influence on the upconversion luminescence emission. With increasing content of PbF2, the intensities of green (529 nm) and red (657 nm) emissions increase slightly, while the green emission (551 nm) increases markedly. These results suggest that PbF2 has an influence on the green (551 nm) emission more than on the green (529 nm) and red (657 nm) emissions.
Received: 19 December 2004
Revised: 16 July 2005
Accepted manuscript online:
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