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Ultrafast third-order optical nonlinearity of several sandwich-type phthalocyaninato and porphyrinato europium complexes
Huang Wen-Tao (黄文涛), Li Yan (李焱), Xiang Hong (向红), Yang Hong (杨宏), Gong Qi-Huang (龚旗煌), Huang Yan-Yi (黄岩谊), Huang Chun-Hui (黄春辉), Jiang Jian-Zhuang (姜建壮)
Chinese Physics, 2005, 14 (11):
2226-2230.
DOI: 10.1088/1009-1963/14/11/014
The third-order optical nonlinearity of two sandwich-type phthalocyaninato and porphyrinato europium complexes, including double- and triple-deckers Eu[Pc(OC5H11)8]2, Eu2(Pc)(TPP)2, Pc=phthalocyanine, TPP=5, 10, 15, 20- tetraphenylporphyrinate), was investigated by using the femtosecond time-resolved optical Kerr gate method at 830 nm wavelength. Their second-order hyperpolarizability is estimated to be 0.74×10-30esu and 3.0×10-30esu respectively. This exhibits an evident enhancement in comparison with 0.47×10-30esu for one-decker Eu(Pc)(acac) (acac=acetylacetonate), which is also measured under the same conditions. The enhancement is attributed to the introduction of lanthanide metal to the large \pi -conjugated system, intermacrocycle interaction and two-photon resonance etc.
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