A high-performance rechargeable Li-O2 battery with quasi-solid-state electrolyte

doi:10.1088/1674-1056/27/7/078201

Abstract

A novel transparent and soft quasi-solid-state electrolyte (QSSE) was proposed and fabricated, which consists of ionic liquid (PYR₁₄TFSI) and nano-fumed silica. The QSSE demonstrates high ionic conductivity of 4.6×10^-4 S/cm at room temperature and wide electrochemical stability window of over 5 V. The Li-O₂ battery using such quasi-solid-state electrolyte exhibits a low charge-discharge overpotential at the first cycle and excellent long-term cyclability over 500 cycles.

Keywords: quasi-solid-state electrolyte Li-O₂ battery

Received: 01 April 2018
Revised: 04 May 2018
Accepted manuscript online:

PACS:	82.47.Aa	(Lithium-ion batteries)
	82.45.Gj	(Electrolytes)
	78.55.Kz	(Solid organic materials)

Fund:

Project supported by the National Key R&D Program of China (Grant Nos. 2016YFB0100300 and 2016YFB0100100), the National Basic Research Program of China (Grant No. 2014CB932300), the Beijing Municipal Science & Technology Commission, China (Grant No. D171100005517001), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA09010000), and the National Natural Science Foundation of China (Grant No. 51502334).

Corresponding Authors: Xiqian Yu, Hong Li
E-mail: xyu@iphy.ac.cn;hli@iphy.ac.cn

Cite this article:

Jia-Yue Peng(彭佳悦), Jie Huang(黄杰), Wen-Jun Li(李文俊), Yi Wang(王怡), Xiqian Yu(禹习谦), Yongsheng Hu(胡勇胜), Liquan Chen(陈立泉), Hong Li(李泓) A high-performance rechargeable Li-O₂ battery with quasi-solid-state electrolyte 2018 Chin. Phys. B 27 078201

[1]	Bruce P G, Freunberger S A, Hardwick L J and Tarascon J M 2012 Nat. Mater. 11 19
[2]	Girishkumar G, Mccloskey B, Luntz A C, Swanson S and Wilcke W 2010 J. Phys. Chem. Lett. 1 2193
[3]	Li F, Kitaura H and Zhou H 2013 Energy Environ. Sci. 6 2302
[4]	Wang X, Zhu D, Song M, Cai S, Zhang L and Chen Y 2014 ACS Appl. Mater. Interfaces 6 11204
[5]	Kitaura H and Zhou H 2015 Sci. Rep. 5 13271
[6]	Wu S, Yi J, Zhu K, Bai S, Liu Y, Qiao Y, et al. 2017 Adv. Energy Mater. 7 1601759
[7]	Yi J, Liu Y, Qiao Y, He P and Zhou H 2017 ACS Energy Lett. 2 1378
[8]	Yang X Y, Xu J J, Chang Z W, et al. 2018 Adv. Energy Mater. 1702242
[9]	Shimano S, Haoshen Zhou A and Honma I 2007 Chem. Mater. 19 5216
[10]	Ito S, Unemoto A, Ogawa H, Tomai T and Honma I 2012 J. Power Sources 208 271
[11]	Matsuo T, Gambe Y, Sun Y and Honma I 2015 Sci. Rep. 4 6084
[12]	Unemoto A, Ogawa H, Gambe Y and Honma I 2014 Electrochim. Acta 125 386
[13]	Mitchell R R, Gallant B M, Yang S H and Thompson C V 2013 J. Phys. Chem. Lett. 4 1060
[14]	Griffith L D, Sleightholme A E S, Mansfield J F, Siegel D J and Monroe C W 2015 ACS Appl. Mater. Interfaces 7 7670
[15]	Aetukuri N B, McCloskey B D, García J M, Krupp L E, Viswanathan V and Luntz A C 2015 Nat. Chem. 7 50
[16]	Guéguen A, Novák P and Berg J 2016 J. Electrochem. Soc. 163 A2545
[17]	Mccloskey B D, Speidel A, Scheffler R, Miller D C, Viswanathan V, Hummelshoj J S, et al. 2012 J. Phys. Chem. Lett. 3 997

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A high-performance rechargeable Li-O2 battery with quasi-solid-state electrolyte

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A high-performance rechargeable Li-O₂ battery with quasi-solid-state electrolyte