Structural phase transitions of tellurium nanoplates under pressure

doi:10.1088/1674-1056/24/3/036401

Abstract

In situ high-pressure angle dispersive x-ray diffraction experiments using synchrotron radiation on Te nanoplates were carried out with a diamond anvil cell at room temperature. The results show that Te-I with a trigonal structure transforms to triclinic Te-Ⅱ at about 4.9 GPa, Te-Ⅱ transforms to monoclinic Te-Ⅲ at about 8.0 GPa, Te-Ⅲ turns to rhombohedral Te-IV at about 23.8 GPa, and Te-IV changes to body centered cubic Te-V at 27.6 GPa. The bulk moduli B₀ of Te nanoplates are higher than those of Te bulk materials.

Keywords: tellurium nanoplates phase transition high pressure

Received: 05 October 2014
Revised: 10 December 2014
Accepted manuscript online:

PACS:	64.70.Nd	(Structural transitions in nanoscale materials)
	61.05.cf	(X-ray scattering (including small-angle scattering))
	64.60.-i	(General studies of phase transitions)

Fund:

Project supported by the State Key Development Program for Basic Research of China (Grant No. 2012CB932302) and the National Natural Science Foundation of China (Grant Nos. 10974235 and 11174336).

Corresponding Authors: Yu Ri-Cheng
E-mail: rcyu@aphy.iphy.ac.cn

Cite this article:

Li Chao (李超), Arfan Bukhtiar, Shen Xi (沈希), Kong Pan-Pan (孔盼盼), Wang Wei-Peng (王伟鹏), Zhao Hao-Fei (赵豪飞), Yao Yuan (姚湲), Zou Bing-Suo (邹炳锁), Li Yan-Chun (李延春), Li Xiao-Dong (李晓东), Liu Jing (刘景), Jin Chang-Qing (靳常青), Yu Ri-Cheng (禹日成) Structural phase transitions of tellurium nanoplates under pressure 2015 Chin. Phys. B 24 036401

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Structural phase transitions of tellurium nanoplates under pressure

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