Liquid-liquid phase transition in confined liquid titanium
Di Zhang(张迪)1, Yunrui Duan(段云瑞)2, Peiru Zheng(郑培儒)1, Yingjie Ma(马英杰)1, Junping Qian(钱俊平)1, Zhichao Li(李志超)1, Jian Huang(黄建)1, Yanyan Jiang(蒋妍彦)1,†, and Hui Li(李辉)1,‡
1 Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China; 2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Abstract We report the layering and liquid-liquid phase transition of liquid titanium confined between two parallel panel walls. Abnormal changes in the volume and the potential energy confirm the existence of the liquid-liquid phase transition of the liquid titanium. The typical feature of the liquid-liquid phase transition is layering, which is induced by the slit size, pressure and temperature. We highlight the fact that the slit size and pressure will determine the number of layers. In addition, with the change in the slit size, the density of the confined liquid expresses a fluctuating law. The phase diagram of the layering transition is drawn to clearly understand the layering. This study provides insights into the liquid-liquid phase transition of liquid metal in a confined space.
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. U1806219 and 52171038), the Special Funding in the Project of the Taishan Scholar Construction Engineering and the Program of Jinan Science and Technology Bureau (Grant No. 2020GXRC019), and Key R&D Projects in Shandong Province, China (Grant No. 2021SFGC1001).
Corresponding Authors:
Yanyan Jiang, Hui Li
E-mail: yanyan.jiang@sdu.edu.cn;lihuilmy@hotmail.com
Cite this article:
Di Zhang(张迪), Yunrui Duan(段云瑞), Peiru Zheng(郑培儒), Yingjie Ma(马英杰), Junping Qian(钱俊平), Zhichao Li(李志超), Jian Huang(黄建), Yanyan Jiang(蒋妍彦), and Hui Li(李辉) Liquid-liquid phase transition in confined liquid titanium 2023 Chin. Phys. B 32 026801
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