Magnetic and ferroelectric properties of Zn and Mn co-doped BaTiO3

doi:10.1088/1674-1056/24/6/067702

Abstract This paper reports an approach to obtaining multiferroic properties in co-doped (Zn:Mn) BaTiO₃ near room temperature. Interestingly, an unusual magnetic hysteresis loop is observed in the co-doped compositions in which the central portion of the loop is squeezed. However, in the composition Ba_0.9Zn_0.1Ti_0.9Mn_0.1O₃, a broad magnetic hysteresis loop is observed. Such a magnetic effect is attributed to the coexistence of antiferromagnetic and ferromagnetic exchange interactions in the system. The observation of the above type of magnetic properties is likely to be due to the presence of exchange interactions between Mn ions. A lossy-type of ferroelectric hysteresis loop is also observed in co-doped ceramic compositions near room temperature.

Keywords: ferroelectrics ceramic ferromagnetic

Received: 26 October 2014
Revised: 07 January 2015
Accepted manuscript online:

PACS:	77.84.-s	(Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)
	81.05.Mh	(Cermets, ceramic and refractory composites)
	76.50.+g	(Ferromagnetic, antiferromagnetic, and ferrimagnetic resonances; spin-wave resonance)

Corresponding Authors: Binod Kumar Roul
E-mail: ims@iopb.res.in

About author: 77.84.-s; 81.05.Mh; 76.50.+g

Cite this article:

Sangram Keshari Das, Binod Kumar Roul Magnetic and ferroelectric properties of Zn and Mn co-doped BaTiO₃ 2015 Chin. Phys. B 24 067702

[1]	Salonitis K, Pandremenos J, Paralikas J and Chryssolouris G 2009 Solid State Commun. 49 1
[15]	Apostolova I N, Apostolov A T, Bahoosh S G and Wesselinowa J M 2013 J. Appl. Phys. 113 203904
[16]	Phan T L, Zhang P, Grinting D, Yu S C, Nghia N X, Dang N V and Lam V D 2012 J. Appl. Phys. 112 013909
[17]	Roul B K 2013 J. Appl. Phys. 113 044101
[22]	Ievtushenko A, Khyzhun O, Shtepliuk I, Tkach V, Lazorenko V and Lashkarev G 2013 Acta Phys. Polon. A 124 858
[23]	Biesingera M C, Laua L W M, Gerson A R and Smart R S C 2010 Appl. Surf. Sci. 257 887
[24]	Shannon R D and Prewitt C T 1969 Acta Cryst. B25 925
[25]	Zheng H, Wang J, Lofland S E, Ma Z, Mohaddes-Ardabili L, Zhao T, Salamanca-Riba L, Shinde S R, Ogale S B, Bai F, Viehland D, Jia Y, Schlom D G, Wuttig M, Roytburd A and Ramesh R 2004 Science 303 661
[26]	Miyakoshi A, Ueno A and Ichikawa M 2001 Appl. Catal. A 219 249
[27]	Xuesong L, Jiqing L, Kun Q, Weixin H and Mengfei L 2009 J. Rare Earths 27 418
[28]	Zhao H W, Wang W N, Wang Y J, Zhan W S and Xiao J Q 2002 J. Appl. Phys. 91 6893
[29]	Brück S, Sort J, Baltz V, Suriñach S, Muñoz J S and Dieny B 2005 Adv. Mater. 17 2978
[30]	Wei X K, Su Y, Sui Y, Zhou Z, Yao Y, Jin C and Yu R 2013 Appl. Phys. Let. 102 242910
[31]	Maurer J A 2003 "I: Structure-Function Analysis of the Mechanosensitive Channel of Large Conductance. II. Design of Novel Magnetic Materials using Crystal Engineering", Ph. D Thesis, California Institute of Technology, USA
[32]	Yu Q S, Wang L, Yu L, Hua L G, Qiang W Y and Nan C 2010 Trans. Nonferrous Met. Soc. China 20 1911
[33]	Das S K, Mishra R N and Roul B K 2014 Appl. Phys. A 116 1897
[34]	Jha P A and Jha A K 2012 J. Alloys Compd. 513 580
[35]	Ferrarelli M C, Tan C C and Sinclair D C 2011 J. Mater. Chem. 21 6292
[36]	Wei X K, Zhang Q H, Li F Y, Jin C Q and Yu R C 2010 J. Alloys Compd. 508 486

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Magnetic and ferroelectric properties of Zn and Mn co-doped BaTiO3

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Magnetic and ferroelectric properties of Zn and Mn co-doped BaTiO₃