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Chin. Phys. B, 2015, Vol. 24(5): 053301    DOI: 10.1088/1674-1056/24/5/053301
Special Issue: TOPICAL REVIEW — Precision measurement and cold matters
TOPICAL REVIEW—Precision measurement and cold matters Prev   Next  

Optical determination of the Boltzmann constant

Cheng Cun-Feng (程存峰), Sun Y. R. (孙羽), Hu Shui-Ming (胡水明)
Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China
Abstract  The Boltzmann constant kB is a fundamental physical constant in thermodynamics. The present CODATA recommended value of kB is 1.3806488(13)× 10-23 J/K (relative uncertainty 0.91 ppm), which is mainly determined by acoustic methods. Doppler broadening thermometry (DBT) is an optical method which determines kBT by measuring the Doppler width of an atomic or molecular transition. The methodology and problems in DBT are reviewed, and DBT measurement using the sensitive cavity ring-down spectroscopy (CRDS) is proposed. Preliminary measurements indicate that CRDS-based DBT measurement can potentially reach an accuracy at the 1 ppm level.
Keywords:  Boltzmann constant      Doppler broadening thermometry      metrology  
Received:  02 December 2014      Revised:  04 February 2015      Accepted manuscript online: 
PACS:  33.20.Ea (Infrared spectra)  
  31.30.J- (Relativistic and quantum electrodynamic (QED) effects in atoms, molecules, and ions)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 91436209, 21225314, and 91221304) and Chinese Academy of Sciences (Grant No. XDB01020000).
Corresponding Authors:  Hu Shui-Ming     E-mail:  smhu@ustc.edu.cn
About author:  33.20.Ea; 31.30.J-

Cite this article: 

Cheng Cun-Feng (程存峰), Sun Y. R. (孙羽), Hu Shui-Ming (胡水明) Optical determination of the Boltzmann constant 2015 Chin. Phys. B 24 053301

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