Crystal structures, phase relationships, and magnetic phase transitions of R5M4 compounds (R=rare earths, M=Si, Ge)

doi:10.1088/1674-1056/22/9/097501

Abstract Our recent studies of the crystal structures, phase transitions, and magnetic properties of intermetallic compounds R₅M₄ (R=rare earths; M=Si, Ge) are reviewed briefly. First, crystal structures, phase relationships, and magnetic properties of several 5:4 compounds, including Nd₅Si_4-xGe_x, Pr₅Si_4-xGe_x, Gd_5-xLa_xGe₄, La₅Si₄, and Gd₅Sn₄, are presented. In particular, the canted spin structures as well as the magnetic phase transitions in Pr₅Si₂Ge₂ and Pr₅Ge₄ investigated by neutron powder diffractions and small-angle neutron scattering are reviewed. Second, the crystal structures and magnetic properties of the most studied compounds Gd₅(Si,Ge)₄ are summarized. The focus is on the parent compound Gd₅Ge₄, which is an amazing material exhibiting magnetic anisotropy, angular dependent spin-flop transition, metastable magnetic response, Griffiths-like phase, thermal effect under pulsed fields, antiferromagnetic and ferromagnetic resonances, pronounced effects of impurities, and high-field induced magnetic transitions.

Keywords: crystal structure phase relationship magnetic phase transition

Received: 17 June 2013
Accepted manuscript online:

PACS:	75.30.Kz	(Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))
	75.30.Sg	(Magnetocaloric effect, magnetic cooling)
	61.66.Dk	(Alloys )

Fund: Project supported by the National Natural Science Foundation of China (Grants Nos. 50025102 and 50631040), the National Basic Research Program of China (Grant No. 2006CB601101), the Exchange Program between NIST and the Chinese Academy of Sciences, and the Natural Science Foundation of Guangxi Province, China (Grant No. 2012GXNSFGA060002).

Corresponding Authors: Rao Guang-Hui
E-mail: rgh@guet.edu.cn

Cite this article:

Ouyang Zhong-Wen (欧阳钟文), Rao Guang-Hui (饶光辉) Crystal structures, phase relationships, and magnetic phase transitions of R₅M₄ compounds (R=rare earths, M=Si, Ge) 2013 Chin. Phys. B 22 097501

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Crystal structures, phase relationships, and magnetic phase transitions of R5M4 compounds (R=rare earths, M=Si, Ge)

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Crystal structures, phase relationships, and magnetic phase transitions of R₅M₄ compounds (R=rare earths, M=Si, Ge)