Abstract This paper studies the influence of the reagent vibration on the reaction O(1D)+HF → HO+F by using a quasi-classical trajectory method on the new ab initio1A' ground singlet potential energy surface (Gómez-Carrasco et al 2007 Chem. Phys. Lett.435 188--193). The product angular distributions which reflect the vector correlation are calculated. Four polarization-dependent differential cross sections (PDDCSs) which are sensitive to many photoinitiated bimolecular reaction experiments are presented in the center of the mass frame, respectively. The differential cross section indicates that the OH product mainly tends to the forward scattering, and other PDDCSs are also influenced by the vibration levels of HF.
Received: 06 January 2009
Revised: 31 May 2009
Accepted manuscript online:
PACS:
82.30.Cf
(Atom and radical reactions; chain reactions; molecule-molecule reactions)
(Classical theories of reactions and/or energy transfer)
Fund: Project supported by the National
Natural Science Foundation of China (Grant No 10574083) and the
Natural Science Foundation of Shandong Province of China (Grant No
Y2006A23), and partially by the National Basic Research Program of
China (Grant No 2006CB8
Cite this article:
Xu Yan(许燕), Zhao Juan(赵娟), Yue Da-Guang(岳大光), Liu Hao(刘浩), Zheng Xiao-Yun(郑晓云), and Meng Qing-Tian(孟庆田) Effect of the reagent vibration on stereodynamics of the reaction O(1D)+HF →F+OH 2009 Chin. Phys. B 18 5308
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.