A-site ordered perovskiteCaCu3Cu2Ir2O12-δ with square-planar and octahedral coordinated Cu ions

doi:10.1088/1674-1056/25/2/020701

Abstract

A novel CaCu₃Cu₂Ir₂O_12-δ polycrystalline sample was synthesized at 8 GPa and 1373 K. Rietveld structural analysis shows that this compound crystallizes in an AA'₃B₄O₁₂-type A-site ordered perovskite structure with space group Im-3. X-ray absorption spectra reveal a +2-charge state for both the square-planar and octahedral coordinated Cu ions, and the valence state of Ir is found to be about +5. Although the A-site Ca and the A' -site Cu²⁺ are 1:3 ordered at fixed atomic positions, the distribution of B-site Cu²⁺ and Ir⁵⁺ is disorderly. As a result, no long-range magnetic ordering is observed at temperatures down to 2 K. Electrical transport and heat capacity measurements demonstrate itinerant electronic behavior. The crystal structure is stable with pressure up to 35.7 GPa at room temperature.

Keywords: high pressure synthesis A-site ordered perovskite valence state magnetic property

Received: 13 October 2015
Revised: 03 November 2015
Accepted manuscript online:

PACS:	07.35.+k	(High-pressure apparatus; shock tubes; diamond anvil cells)
	61.05.cj	(X-ray absorption spectroscopy: EXAFS, NEXAFS, XANES, etc.)
	75.20.-g	(Diamagnetism, paramagnetism, and superparamagnetism)

Fund:

Project supported by the National Basic Research Program of China (Grant No. 2014CB921500), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB07030300), and the National Natural Science Foundation of China (Grant No. 11574378).

Corresponding Authors: You-Wen Long
E-mail: wangqt@qdu.edu.cn

Cite this article:

Qing Zhao(赵庆), Yun-Yu Yin(殷云宇), Jian-Hong Dai(戴建洪), Xi Shen(沈希), Zhi-Wei Hu(胡志伟), Jun-Ye Yang(杨俊叶), Qing-Tao Wang(王清涛), Ri-Cheng Yu(禹日成), Xiao-Dong Li(李晓东), You-Wen Long(龙有文) A-site ordered perovskiteCaCu₃Cu₂Ir₂O_12-δ with square-planar and octahedral coordinated Cu ions 2016 Chin. Phys. B 25 020701

[1]	Shiraki H, Saito T, Yamada T, Tsujimoto M, Azuma M, Kurata H, Isoda S, Takano M and Shimakawa Y 2007 Phys. Rev. B 76 140403(R)
[2]	Kayser P, Retuerto M, Sanchez-Benıez J, Martínez-Lope M J, Fernández-Díaz M T and Alonso J A 2012 J. Phys.: Condens. Matter 24 496002
[3]	Shimakawa Y and Saito T 2012 Phys. Status Solidi B 249 423
[4]	Koitzsch A, Blumberg G, Gozar A, Dennis B, Ramirez A P, Trebst S, and Wakimoto S 2002 Phys. Rev. B 65 052406
[5]	Long Y W, Hayashi N, Saito T, Azuma M, Muranaka S and Shimakawa Y 2009 Nature 458 07816
[6]	Long Y W, Saito T, Tohyama T, Oka K, Azuma M and Shimakawa Y 2009 Inorg. Chem. 48 8489
[7]	Long Y W and Shimakawa Y 2010 New J. Phys. 12 063029
[8]	Hao X F, Xu Y H, Gao F M, Zhou D F and Meng J 2009 Phys. Rev. B 79 113101
[9]	Yamada I, Tsuchida K, Ohgushi K, Hayashi N, Kim J, Tsuji N, Takahashi R, Matsushita M, Nishiyama N, Inoue T, Irifune T, Kato K, Takata M and Takano M 2011 Angew. Chem. Int. Ed. 50 6579
[10]	Cai L G, Liu F M and Zhong W W 2010 Chin. Phys. B 19 097101
[11]	Han D D, Gao W, Li N N, Tang R L, Li H, Ma Y M, Cui Q L, Zhu P W and Wang X 2013 Chin. Phys. B 22 059101
[12]	Fang Y, Yan S M, Qiao W, Wang W, Wang D H and Du Y W 2014 Chin. Phys. B 23 117501
[13]	Subramanian M A, Li D, Duan N, Reisner B A and Sleight A W 2000 J. Solid State Chem. 151 323
[14]	Larson A C and Von Dreele R B 2004 General Structure Analysis System (GSAS), Los Alamos National Laboratory Report No. LAUR 86-748.
[15]	Mao H K, Xu J and Bell P M 1986 J. Geophys. Res. 91 4673
[16]	Byeon S H, Lee S S, Parise J B, Woodward P M and Hur N H 2004 Chem. Mater. 16 3697
[17]	Byeon S H, Lee S S, Parise J B, Woodward P M and Hur N H 2005 Chem. Mater. 17 3552
[18]	Byeon S H, Lee S S, PariseJ B and Woodward P M 2006 Chem. Mater. 18 3873
[19]	Anderson M T, Greenwood K B, Taylor G A and Poeppelmeiert K R 1993 Prog. Solid State. Chem. 22 197
[20]	Cheng J G, Zhou J S, Yang Y F, Zhou H D, Matsubayashi K, Uwatoko Y, MacDonald A and Goodenough J B 2013 Phys. Rev. Lett. 111 176403
[21]	Salluzzo M, Ghiringhelli G, Brookes N B, De Luca G M, Fracassi F and Vaglio R 2007 Physica C 460 971
[22]	Huang M J, Deng G, Chin Y Y, Hu Z, Cheng J G, Chou F C, Conder K, Zhou J S, Pi T W, Goodenough J B, Lin H J and Chen C T 2013 Phys. Rev. B 88 014520
[23]	Hu Z, Drechsler S L, Malek J, Rosner H, Neudert R, Knupfer M, Golden M S, Fink J, Karpinski J and Kaindl G 2002 Europhys. Lett. 59 135
[24]	Hu Z, Mazumdar Chandan, Kaindl G, de Groot F M F, Warda S A and Reinen D 1998 Chem. Phys. Lett. 297 321
[25]	Chen C T, Tjeng L H, Kwo J, Kao H L, Rudolf P, Sette F and Fleming R M 1992 Phys. Rev. Lett. 68 2543
[26]	Meyers D, Mukherjee Swarnakamal, Cheng J G, Middey S, Zhou J S, Goodenough J B, Gray B A, Freeland J W, Saha-Dasgupta T and Chakhalian J 2013 Sci. Rep. 3 1834
[27]	Mugavero III S J, Smith M D, Yoon W S and Loye H Z 2009 Angew. Chem. Int. Ed. 48 215
[28]	Shimakawa Y 2008 Inorg. Chem. 47 8562
[29]	Cao G, Qi T F, Li L, Terzic J S, Yuan J, DeLong L E, Murthy G and Kaul R K 2014 Phys. Rev. Lett. 112 056402
[30]	Vasala S, Yamauchi H and Karppinen M 2014 J. Solid State Chem. 220 28
[31]	Mizumaki M, Saito T, Shiraki H and Shimakawa Y 2009 Inorg. Chem. 48 3499
[32]	Krohns S, Lu J, Lunkenheimer P, Brize V, Autret-Lambert C, Gervais M, Gervais F, Bouree F, Porcher F and Loidl 2009 Eur. Phys. J. B 72 173
[33]	Shimakawa Y, Shiraki H and Saito T 2008 J. Phys. Soc. Jpn. 77 113702
[34]	Kim Y J, Wakimoto S, Shapiro S M, Gehring P M and Ramirez A P 2002 Solid State Commun. 121 625
[35]	Paul A K, Jansen M, Yan B H, Felser C, Reehuis M and Abdala P M 2013 Inorg. Chem. 52 6713
[36]	Yuan C L, Zhu Y and Ong P P 2002 J. Appl. Phys. 91 4421
[37]	Sleight A W 1974 Mater. Res. Bull. 9 1177

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A-site ordered perovskiteCaCu3Cu2Ir2O12-δ with square-planar and octahedral coordinated Cu ions

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A-site ordered perovskiteCaCu₃Cu₂Ir₂O_12-δ with square-planar and octahedral coordinated Cu ions