Li-ion batteries: Phase transition

doi:10.1088/1674-1056/25/1/016104

Abstract

Progress in the research on phase transitions during Li⁺ extraction/insertion processes in typical battery materials is summarized as examples to illustrate the significance of understanding phase transition phenomena in Li-ion batteries. Physical phenomena such as phase transitions (and resultant phase diagrams) are often observed in Li-ion battery research and already play an important role in promoting Li-ion battery technology. For example, the phase transitions during Li⁺ insertion/extraction are highly relevant to the thermodynamics and kinetics of Li-ion batteries, and even physical characteristics such as specific energy, power density, volume variation, and safety-related properties.

Keywords: Li-ion batteries phase transition phase diagram electrodes

Received: 05 June 2015
Revised: 28 August 2015
Accepted manuscript online:

PACS:	61.66.Fn	(Inorganic compounds)
	61.50.Ah	(Theory of crystal structure, crystal symmetry; calculations and modeling)
	61.05.cp	(X-ray diffraction)

Fund:

Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA050906) and the National Natural Science Foundation of China (Grant Nos. 51272175 and 21301127).

Corresponding Authors: Lianqi Zhang
E-mail: tianjinzhanglq@163.com

Cite this article:

Peiyu Hou(侯配玉), Geng Chu(褚赓), Jian Gao(高健), Yantao Zhang(张彦涛), Lianqi Zhang(张联齐) Li-ion batteries: Phase transition 2016 Chin. Phys. B 25 016104

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