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La-doped BiFeO3：Synthesis and multiferroic property study |
| Lin Peng-Ting (蔺鹏婷)a, Li Xiang (李祥)a, Zhang Li (张丽)a, Yin Jin-Hua (阴津华)b, Cheng Xing-Wang (程兴旺)a, Wang Zhi-Hong (王志宏)c, Wu Yu-Chuan (吴玉娟)d, Wu Guang-Heng (吴光恒)c |
a School for Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
b Physics Department, University of Science & Technology of Beijing, Beijing 100083, China;
c State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
d Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taiwan, China |
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Abstract A new sol-foam-gel method was developed to fabricate La-doped BiFeO3 multiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO3 results in its structure changing from rhombohedral to orthorhombic. A study of other property changes indicates that La-doping in BiFeO3 enhances its ferromagnetism and ferroelectricity. A temperature-dependent magnetization study suggests that the magnetic property of La-doped BiFeO3 samples varied from antiferromagnetic to ferromagnetic as the content of La-doped into BiFeO3 increased from 0 to 20%. Unique temperature-dependent zero field cooling (ZFC) and field cooling (FC) magnetization behaviors were observed in 15% La-doped BiFeO3 – its ZFC temperature-dependent magnetization being ferromagnetic and its FC temperature-dependent magnetization being antiferromagnetic. A possible mechanism of such an interesting M-T behavior is discussed.
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Received: 25 September 2013
Revised: 30 October 2013
Accepted manuscript online:
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PACS:
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77.80.Dj
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(Domain structure; hysteresis)
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77.84.-s
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(Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)
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81.20.Ka
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(Chemical synthesis; combustion synthesis)
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Corresponding Authors:
Li Xiang
E-mail: aihyoo@bit.edu.cn
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| About author: 77.80.Dj; 77.84.-s; 81.20.Ka |
Cite this article:
Lin Peng-Ting (蔺鹏婷), Li Xiang (李祥), Zhang Li (张丽), Yin Jin-Hua (阴津华), Cheng Xing-Wang (程兴旺), Wang Zhi-Hong (王志宏), Wu Yu-Chuan (吴玉娟), Wu Guang-Heng (吴光恒) La-doped BiFeO3：Synthesis and multiferroic property study 2014 Chin. Phys. B 23 047701
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