Abstract The laser-induced fluorescence excitation spectra of jet-cooled CuF have been recorded in the range of 19000-21470cm$^{-1}$, in which the CuF radicals were produced by the reaction of SF$_6$ with copper atoms from a dc discharge-sputtering source under supersonic jet conditions. Eight observed vibronic transition bands have been assigned as the transition from the ground state $X(^1\Sigma^+$) to $B(^1\Sigma^+$), $C(^1\Pi$) and an unreported upper state. The rotational structure of all observed bands has been analysed at the estimated rotational temperature 80K. We determined the newly observed band to be the ($^1\Pi, v=1)-X(^1\Sigma^+v=0$) transition according to the character of the rotational structure and the isotopic shift analysis. In addition, the lifetimes of the states involved in these bands were measured.
Received: 10 February 2003
Revised: 24 March 2003
Accepted manuscript online:
Fund: Project supported by the National Natural Science Foundation of China (Grant No 20203018), the National Key Basic Research Special Foundation of China (Grant No G1999075304), and Chinese Academy of Science.
Cite this article:
Zhang Xiao-Peng (张霄鹏), Guo Jing-Ru (郭静茹), Wang Ting-Ting (王婷婷), Pei Lin-Sen (裴林森), Chen Cong-Xiang (陈从香), Chen Yang (陈旸) Laser spectroscopy of jet-cooled CuF in visible region 2003 Chinese Physics 12 851
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