Negative thermal expansion and photoluminescence in solid solution (HfSc)0.83W2.25P0.83O12δ

doi:10.1088/1674-1056/26/10/106501

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Abstract

A solid solution of (HfSc)_0.83W_2.25P_0.83O_12-δ is synthesized by the high-temperature, solid-state reaction and fast-quenching method. It is shown that it possesses an orthorhombic structure with space group Pmmm (47) and exhibits negative thermal expansion (NTE) property with low anisotropy in thermal expansion. The coefficients of thermal expansion (CTEs) for a, b, and c axes are -1.41×10^-6 K^-1, -2.23×10^-6 K^-1, and -1.87×10^-6 K^-1, respectively. This gives rise to volume and linear CTEs of -3.10×10^-6 K^-1 and -1.03×10^-6 K^-1, respectively. Besides, it exhibits also intense photoluminescence from 360 nm to about 600 nm. The mechanism of NTE and the correlation of the PL with axial thermal expansion property are discussed.

Key words： negative thermal expansion solid solution photoluminescence

Received: 18 May 2017

PACS:	65.40.De	(Thermal expansion; thermomechanical effects)
	81.05.Je	(Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))
	61.50.-f	(Structure of bulk crystals)
	78.55.-m	(Photoluminescence, properties and materials)

Fund:

Project supported by the National Natural Science Foundation of China (Grant Nos. 11574276, 51302249, and 11405028) and the Fundamental Research Fund for the Central Universities, China.

Corresponding Authors: Yuan Liang

E-mail: yliang@dhu.edu.cn

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	Yuan Liang
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	Er-Jun Liang

Cite this article:

Yuan Liang,Yong-Guang Cheng,Xiang-Hong Ge et al . Negative thermal expansion and photoluminescence in solid solution (HfSc)_0.83W_2.25P_0.83O_12δ[J]. Chin. Phys. B, 2017, 26(10):106501.

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http://cpb.iphy.ac.cn/EN/10.1088/1674-1056/26/10/106501 OR http://cpb.iphy.ac.cn/EN/Y2017/V26/I10/106501

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