Electric properties and phase transition behavior in lead lanthanum zirconate stannate titanate ceramics with low zirconate content

doi:10.1088/1674-1056/24/11/117702

Abstract The phase transitions, dielectric properties, and polarization versus electric field (P-E) hysteresis loops of Pb_0.97La_0.02(Zr_0.42Sn_0.58-xTi_x)O₃ (0.13 ≤ x ≤ 0.18) (PLZST) bulk ceramics were systematically investigated. This study exhibited a sequence of phase transitions by analyzing the change of the P-E hysteresis loops with increasing temperature. The antiferroelectric (AFE) to ferroelectric (FE) phase boundary of PLZST with the Zr content of 0.42 was found to locate at the Ti content between 0.14 and 0.15. This work is aimed to improve the ternary phase diagram of lanthanum-doped PZST with the Zr content of 0.42 and will be a good reference for seeking high energy storage density in the PLZST system with low-Zr content.

Keywords: PLZST ceramics ferroelectricity antiferroelectricity phase transition

Received: 23 March 2015
Revised: 19 May 2015
Accepted manuscript online:

PACS:	77.80.-e	(Ferroelectricity and antiferroelectricity)
	77.80.B-	(Phase transitions and Curie point)
	77.84.Cg	(PZT ceramics and other titanates)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51202273, 11204304, and 11304334) and the Science and Technology Commission of Shanghai Municipality, China (Grant No. 14DZ2261000).

Corresponding Authors: Zeng Tao, Chen Xue-Feng
E-mail: zengtao@shiep.edu.cn;xfchen@mail.sic.ac.cn

Cite this article:

Zeng Tao (曾涛), Lou Qi-Wei (漏琦伟), Chen Xue-Feng (陈学锋), Zhang Hong-Ling (张红玲), Dong Xian-Lin (董显林), Wang Gen-Shui (王根水) Electric properties and phase transition behavior in lead lanthanum zirconate stannate titanate ceramics with low zirconate content 2015 Chin. Phys. B 24 117702

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Electric properties and phase transition behavior in lead lanthanum zirconate stannate titanate ceramics with low zirconate content

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