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Chinese Physics, 2006, Vol. 15(9): 2158-2164    DOI: 10.1088/1009-1963/15/9/042
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses

Zhao Chun(赵纯)a)b)†, Zhang Qin-Yuan(张勤远)a)‡ , Pan Yue-Xiao(潘跃晓)a), and Jiang Zhong-Hong(姜中宏)a)
a Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology (Ministry of Education) and Institute of Optical Communications, South China University of Technology, Guangzhou 510641, China; b College of Applied Physics, South China University of Technology, Guangzhou 510641, China
Abstract  Er3+-doped tellurite glasses with molar compositions of xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2-- 60TeO2--0.3Er2O3 (x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability and optical properties of Er3+-doped tellurite glasses have been discussed. It is noted that the incorporation of Nb2O5 (x=5) increases the thermal stability of tellurite glasses significantly. Er3+-doped niobium tellurite glasses exhibit a large stimulated emission cross-section (7.2×10-21- 10.7×10-21~cm2 and the gain bandwidth, FWHM×$\sigma^{\rm peak}_{\rm e}$  (274×0-28 - 480×10-28 cm3), which are significantly higher than that of silicate and phosphate glasses. In addition, the intensity of upconversion luminescence of the Er3+-doped niobium tellurite glasses decreases rapidly with increasing Nb2O5 content. As a result, Er3+-doped niobium tellurite glasses might be a potential candidate for developing laser or optical amplifier devices.
Keywords:  glasses      thermal analysis      optical materials      optical properties  
Received:  28 December 2005      Revised:  09 May 2006      Accepted manuscript online: 
PACS:  75.60.Ej (Magnetization curves, hysteresis, Barkhausen and related effects)  
  75.10.Dg (Crystal-field theory and spin Hamiltonians)  
  75.30.Gw (Magnetic anisotropy)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No 50472053), New Century Excellent Talent Program in University of China (Grant Nos 04-0821 and 04-0823), Guangzhou Science and Technology Program of China (Grant No 2004Z2-D0131), and Youth Nature Science Foundation of South China University of Technology (Grant No 123-E5040900).

Cite this article: 

Zhao Chun(赵纯), Zhang Qin-Yuan(张勤远), Pan Yue-Xiao(潘跃晓), and Jiang Zhong-Hong(姜中宏) Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses 2006 Chinese Physics 15 2158

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