Structure phase transformation and equation of state of cerium metal under pressures up to 51 GPa

doi:10.1088/1674-1056/25/4/046401

Abstract This study presents high pressure phase transitions and equation of states of cerium under pressures up to 51 GPa at room temperature. The angle-dispersive x-ray diffraction experiments are carried out using a high energy synchrotron x-ray source. The bulk moduli of high pressure phases of cerium are calculated using the Birch-Murnaghan equation. We discuss and correct several previous controversial conclusions, which are caused by the measurement accuracy or personal explanation. The c/a axial ratio of ε-Ce has a maximum value at about 29 GPa, i.e., c/a ≈ 1.690.

Keywords: cerium equation of state high pressure phase transition

Received: 24 September 2015
Revised: 04 December 2015
Accepted manuscript online:

PACS:

64.30.Ef

(Equations of state of pure metals and alloys)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. NSAF.U1330115) and the National Major Scientific Instrument and Equipment Development Project of China (Grant No. 2012YQ130234).

Corresponding Authors: Peng-Cheng Zhang, Qi-Liang Cui
E-mail: zpc113@sohu.com;cql@jlu.edu.cn

Cite this article:

Ce Ma(马策), Zuo-Yong Dou(窦作勇), Hong-Yang Zhu(祝洪洋), Guang-Yan Fu(付广艳), Xiao Tan(谈笑), Bin Bai(白彬), Peng-Cheng Zhang(张鹏程), Qi-Liang Cui(崔啟良) Structure phase transformation and equation of state of cerium metal under pressures up to 51 GPa 2016 Chin. Phys. B 25 046401

[1]	Xu J A and Bi Y 2012 Physics 41 218 (in Chinese)
[2]	Hecker S S 2000 Los Alamos Science 26 290
[3]	Nikolaev A V and Tsvyashchenko A V 2012 Physics-Uspekhi. 55 657
[4]	Dmitriev V P, Kuznetsov A Yu, Bandilet O, Bouvier P, Dubrovinsky L, Machon D and Weber H P 2004 Phys. Rev. B 70 014104
[5]	Beecroft R I and Swenson C A 1960 J. Phys. Chem. Solids 15 234
[6]	Jeong I K, Darling T W, Graf M J, Proffen T and Heffner R H 2004 Phys. Rev. Lett. 92 105702
[7]	Lipp M J, Jackson D, Cynn H, Aracne C, Evans W J and McMahan A K 2008 Phys. Rev. Lett. 101 165703
[8]	Allen J W and Martin R M 1982 Phys. Rev. Lett. 49 1106
[9]	Johansson B 1974 Philos. Mag. 30 469
[10]	McMahon M I and Nelmes R J 1997 Phys. Rev. Lett. 78 3884
[11]	McMahon M I and Nelmes R J 1998 Rev. High Pressure Sci. Technol. 17 313
[12]	Gu G L, Vohra Y K and Brister K E 1995 Phys. Rev. B 52 9107
[13]	Tsiok O B and Khvostantsev L G 2001 J. Exp. Theor. Phys. 6 93
[14]	Olsen J S, Gerward L, Benedict U and Itié J P 1985 Physica B 133 129
[15]	Vohra Y K, Beaver S L, Akella J, Ruddle C A and Weir S T 1999 J. Appl. Phys. 85 2451
[16]	Clark S M 2002 Crystallogr Rev. 8 57
[17]	Mao H K, Xu J and Bell P M 1986 J. Geophys. Res. 91 4673
[18]	Murnaghan F D 1944 Proc. Nati. Acad. Sci. USA 30 244
[19]	Perdew J D, Burke K and Ernzerhof M 1996 Phys. Rev. Lett. 77 3865
[20]	Tian M F, Deng X, Fang Z and Dai X 2011 Phys. Rev. B 84 205124
[21]	Zachariasen W H and Ellinger F H 1977 Acta Cryst. A33 155
[22]	Endo S, Fujioka N and Sasaki H 1977 J. Phys. Soc. Jpn. 42 882
[23]	Ravindran P, Nordström L, Ahuja R, Wills J M, Johansson B and Eriksson O 1998 Phys. Rev. B 57 2091

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Structure phase transformation and equation of state of cerium metal under pressures up to 51 GPa

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