Controlled synthesis of ferromagnetic MnSex particles

doi:10.1088/1674-1056/25/10/107405

Abstract The MnSe_x (x=1,2) nanoparticles were synthesized under hydrothermal condition, by reaction of the reduced selenium and Mn²⁺ ion in the presence of hydrazine and acetic acid. By precisely controlling the pH value of the solution, a series of MnSe_x particles were synthesized. The structure and morphology of as-prepared particles were examined with x-ray diffractometer (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The average sizes of as-prepared particles varied from nanoscale to microscale with pH value increase. Furthermore, the nucleation and growth mechanism associated with pH values were discussed, which can be applied to the hydrothermal synthesis of metal chalcogenide in general. Finally, the optical and magnetic properties of as-prepared particles were measured. All as-made particles exhibit a ferromagnetic behavior with low coercivity and remanence at room temperature.

Keywords: transition metal chalcogenide phase transition controlled synthesis

Received: 29 February 2016
Revised: 14 July 2016
Accepted manuscript online:

PACS:	74.70.Xa	(Pnictides and chalcogenides)
	75.25.-j	(Spin arrangements in magnetically ordered materials (including neutron And spin-polarized electron studies, synchrotron-source x-ray scattering, etc.))

Fund: Project supported by the National Basic Research Program of China (Grant No. 2015CB921502), the National Natural Science Foundation of China (Grant Nos. 11474184 and 11627805), the 111 Project (Grant No. B13029), and the Fundamental Research Funds of Shandong University, China.

Corresponding Authors: Shishou Kang
E-mail: skang@sdu.edu.cn

Cite this article:

Junjie Sun(孙俊杰), Chao Li(李超), Duo Chen(陈铎), Shishou Kang(康仕寿), Guolei Liu(刘国磊), Shuyun Yu(于淑云), Guangbing Han(韩广兵), Liangmo Mei(梅良模) Controlled synthesis of ferromagnetic MnSe_x particles 2016 Chin. Phys. B 25 107405

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Controlled synthesis of ferromagnetic MnSex particles

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Controlled synthesis of ferromagnetic MnSe_x particles