Effects of Ni substitution on multiferroic properties in Bi5FeTi3O15 ceramics

doi:10.1088/1674-1056/ac1b92

Abstract The single-phase multiferroic Bi₅Fe_1-xNi_xTi₃O₁₅ (BFNT-x, x=0, 0.1, 0.2, 0.3, 0.4, and 0.5) ceramics were synthesized by a sol-gel auto-combustion method, and their microstructures, ferroelectric, magnetic, and dielectric properties were investigated in detail. All samples belong to layer-perovskited Aurivillius phase containing four perovskite units sandwiched between two Bi-O layers. Ni substitution can not only improve ferroelectricity but also enhance the magnetic properties. The BFNT-0.2 sample shows the largest remnant polarization (2P_r ～ 11.6 μC/cm²) and the highest remnant magnetization (2M_r ～ 0.244 emu/g). The enhancement of the magnetic properties may mainly originate from the spin canting of Fe/Ni-O octahedra via Dzyaloshinskii-Moriya (DM) interaction. In order to explore the influence of valance state of magnetic ions on the properties, the x-ray photoelectron spectroscopy was carried out. Furthermore, structural, ferroelectric, and magnetic transitions were also investigated.

Keywords: layer-perovskited oxides ferroelectricity weak ferromagnetism phase transition

Received: 02 July 2021
Revised: 31 July 2021
Accepted manuscript online: 07 August 2021

PACS:	77.80.-e	(Ferroelectricity and antiferroelectricity)
	77.80.B-	(Phase transitions and Curie point)
	91.60.Pn	(Magnetic and electrical properties)
	75.47.Lx	(Magnetic oxides)

Corresponding Authors: Hui Sun
E-mail: hsun@yzu.edu.cn

Cite this article:

Hui Sun(孙慧), Jiaying Niu(钮佳颖), Haiying Cheng(成海英), Yuxi Lu(卢玉溪), Zirou Xu(徐紫柔), Lei Zhang(张磊), and Xiaobing Chen(陈小兵) Effects of Ni substitution on multiferroic properties in Bi₅FeTi₃O₁₅ ceramics 2021 Chin. Phys. B 30 107701

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Effects of Ni substitution on multiferroic properties in Bi5FeTi3O15 ceramics

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Effects of Ni substitution on multiferroic properties in Bi₅FeTi₃O₁₅ ceramics