Conductivity and applications of Li-biphenyl-1, 2-dimethoxyethane solution for lithium ion batteries

doi:10.1088/1674-1056/26/7/078201

Abstract

The total conductivity of Li-biphenyl-1,2-dimethoxyethane solution (Li_xBp(DME)_9.65, Bp=biphenyl, DME=1,2-dimethoxyethane, x=0.25, 0.50, 1.00, 1.50, 2.00) is measured by impedance spectroscopy at a temperature range from 0℃ to 40℃. The Li_1.50Bp(DME)_9.65 has the highest total conductivity 10.7 mS/cm. The conductivity obeys Arrhenius law with the activation energy (E_a(x=0.50)=0.014 eV, E_a(x=1.00)=0.046 eV). The ionic conductivity and electronic conductivity of Li_xBp(DME)_9.65 solutions are investigated at 20℃ using the isothermal transient ionic current (ITIC) technique with an ion-blocking stainless steal electrode. The ionic conductivity and electronic conductivity of Li_1.00Bp(DME)_9.65 are measured as 4.5 mS/cm and 6.6 mS/cm, respectively. The Li_1.00Bp(DME)_9.65 solution is tested as an anode material of half liquid lithium ion battery due to the coexistence of electronic conductivity and ionic conductivity. The lithium iron phosphate (LFP) and Li_1.5Al_0.5Ti_1.5(PO₄)₃ (LATP) are chosen to be the counter electrode and electrolyte, respectively. The assembled cell is cycled in the voltage range of 2.2 V–3.75 V at a current density of 50 mA/g. The potential of Li_1.00Bp(DME)_9.65 solution is about 0.3 V vs. Li⁺/Li, which indicates the solution has a strong reducibility. The Li_1.00Bp(DME)_9.65 solution is also used to prelithiate the anode material with low first efficiency, such as hard carbon, soft carbon and silicon.

Keywords: lithium solution ionic and electronic conductivity flow lithium ion battery prelithiation

Received: 03 February 2017
Revised: 21 March 2017
Accepted manuscript online:

PACS:	82.47.Aa	(Lithium-ion batteries)
	82.45.Fk	(Electrodes)
	72.60.+g	(Mixed conductivity and conductivity transitions)

Fund:

Project supported by the National Natural Science Foundation of China (Grant No.52315206),the Ministry of Science and Technology of China (Grant No.2016YFB0100100),and the Beijing Municipal Science and Technology Commission,China (Grant No.D151100003115003).

Corresponding Authors: Hong Li
E-mail: hli@iphy.ac.cn

Cite this article:

Geng Chu(褚赓), Bo-Nan Liu(刘柏男), Fei Luo(罗飞), Wen-Jun Li(李文俊), Hao Lu(陆浩), Li-Quan Chen(陈立泉), Hong Li(李泓) Conductivity and applications of Li-biphenyl-1, 2-dimethoxyethane solution for lithium ion batteries 2017 Chin. Phys. B 26 078201

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Conductivity and applications of Li-biphenyl-1, 2-dimethoxyethane solution for lithium ion batteries

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