Influence of Al3+ doping on the energy levels and thermal property of the 3.5MgO·0.5MgF2·GeO2:Mn4+ red-emitting phosphor

doi:10.1088/1674-1056/24/8/087802

Abstract A series of Al³⁺-doped 3.5MgO·0.5MgF₂·GeO₂:Mn⁴⁺ red-emitting phosphors is synthesized by high temperature solid-state reaction. The broad excitation band at 300 nm-380 nm, resulting from the ⁴A₂ → ⁴T₁ transition of Mn⁴⁺, exhibits a blue shift with the increase of Al₂O₃ content. The observation of the decreased Mn⁴⁺-O^2- distance is explained by the crystal field theory. The temperature-dependent photoluminescence spectra with various amounts of Al₂O₃ content are comparatively measured and the calculation shows that the activation energy increases up to 0.41 eV at the Al₂O₃ content of 0.1 mol. The maximum phonon densities of state for these samples are calculated from Raman spectra and they are correlated with the thermal properties.

Keywords: phosphors photoluminescence thermal properties

Received: 21 January 2015
Revised: 19 March 2015
Accepted manuscript online:

PACS:	78.55.-m	(Photoluminescence, properties and materials)
	33.50.-j	(Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion))
	65.40.-b	(Thermal properties of crystalline solids)

Fund: Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA014201), the Natural Science Foundation of Tianjin City, China (Grant Nos. 11JCYBJC00300 and 14JCZDJC31200), and the National Key Foundation for Exploring Scientific Instrument of China (Grant No. 2014YQ120351).

Corresponding Authors: Li Lan
E-mail: lilan@tjut.edu.cn

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Yuan Lin-lin (苑琳琳), Zhang Xiao-Song (张晓松), Xu Jian-Ping (徐建萍), Sun Jian (孙健), Jin Han (金含), Liu Xiao-Juan (刘晓娟), Li Lin-Lin (李霖霖), Li Lan (李岚) Influence of Al³⁺ doping on the energy levels and thermal property of the 3.5MgO·0.5MgF₂·GeO₂:Mn⁴⁺ red-emitting phosphor 2015 Chin. Phys. B 24 087802

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Influence of Al3+ doping on the energy levels and thermal property of the 3.5MgO·0.5MgF2·GeO2:Mn4+ red-emitting phosphor

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Influence of Al³⁺ doping on the energy levels and thermal property of the 3.5MgO·0.5MgF₂·GeO₂:Mn⁴⁺ red-emitting phosphor