CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Prev
Next
|
|
|
Probing the thermoelectric transport properties of n-type Bi2Te3 close to the limit of constitutional undercooling |
Feng Song-Ke (冯松科), Li Shuang-Ming (李双明), Fu Heng-Zhi (傅恒志) |
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China |
|
|
Abstract Bulk n-type Bi2Te3 single crystals with optimized chemical composition were successfully prepared by a high temperature-gradient directional solidification method. We investigate the influence of alloy microstructure, chemical composition, and growth orientation on the thermoelectric transport properties. The results show that the composition of single-crystal Bi2Te3 alloy, along the c axis direction, could be slightly tuned by changing the growth rate of the crystal. At a rate of 18 mm/h, the formed Bi2Te3 crystal exhibits good thermoelectric properties. At 300 K, a maximum Seebeck coefficient of -245 uV/K and an electrical conductivity of 5.6×104 S/m are acquired. The optimal power factor is obtained as 3.3× 10-3 W/K2m, with a figure of merit of 0.74. It can be attributed to the increased tellurium allocation in the Bi2Te3 alloys, as verified well by the density functional theory calculations.
|
Received: 10 July 2014
Revised: 07 August 2014
Accepted manuscript online:
|
PACS:
|
72.15.Jf
|
(Thermoelectric and thermomagnetic effects)
|
|
81.30.Fb
|
(Solidification)
|
|
74.25.F-
|
(Transport properties)
|
|
32.10.Dk
|
(Electric and magnetic moments, polarizabilities)
|
|
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 51074127) and the Research Fund of the State Key Laboratory of Solidification Processing of Northwestern Polytechnical University, China (Grant No. SKLSP201010). |
Corresponding Authors:
Li Shuang-Ming
E-mail: lsm@nwpu.edu.cn
|
Cite this article:
Feng Song-Ke (冯松科), Li Shuang-Ming (李双明), Fu Heng-Zhi (傅恒志) Probing the thermoelectric transport properties of n-type Bi2Te3 close to the limit of constitutional undercooling 2014 Chin. Phys. B 23 117202
|
[1] |
Chen Y L, Analytis J G, Chu J H, Liu Z K, Mo S K, Qi X L, Zhang H J, Lu D H, Dai X, Fang Z, Zhang S C, Fisher I R, Hussain Z and Shen Z X 2009 Science 325 178
|
[2] |
Hamdou B, Kimling J, Dorn A, Pippel E, Rostek R, Woias P and Nielsch K 2013 Adv. Mater. 25 239
|
[3] |
Min Y, Roh J W, Yang H, Park M, Kim S, Hwang S, Lee S M, Lee K H and Jeong U 2013 Adv. Mater. 25 1425
|
[4] |
Zhang H, Liu C X, Qi X L, Dai X, Fang Z and Zhang S C 2009 Nat. Phys. 5 438
|
[5] |
Heinz N A, Ikeda T and Snyder G J 2012 Acta Mater. 60 4461
|
[6] |
Wang G, Zhu X G, Sun Y Y, et al. 2011 Adv. Mater. 2929
|
[7] |
Rowe D M 1995 CRC Handbook of Thermoelectrics (Boca Raton, Florida: CRC press) pp. 216-218
|
[8] |
Nolas G S, Sharp J and Goldsmid J 2001 Thermoelectrics: Basic Principles and New Materials Developments (Berlin: Springer) pp. 59-87
|
[9] |
Cosgrove G J, McHugh J P and Tiller W A 1961 J. Appl. Phys. 32 621
|
[10] |
Shen J J, Hu L P, Zhu T J and Zhao X B 2011 Appl. Phys. Lett. 99 124102
|
[11] |
Kim D H, Kim C, Heo S H and Kim H Y 2011 Acta Mater. 59 405
|
[12] |
Ni H L, Zhu T J and Zhao X B 2005 Mater. Sci. Eng. B 117 119
|
[13] |
Miura S, Sato Y, Fukuda K, Nishimura K and Ikeda K 2000 Mater. Sci. Eng. A 277 244
|
[14] |
Nassary M M, Shaban H T and El-Sadek M S 2009 Mater. Chem. Phys. 113 385
|
[15] |
Yamashita O and Tomiyoshi S 2003 J. Appl. Phys. 93 368
|
[16] |
Zou H L, Rowe D M and Min G 2001 J. Cryst. Growth 222 82
|
[17] |
Ha H P, Hyun D B, Byun J Y and Oh Y J 2002 J. Appl. Phys. 37 4691
|
[18] |
Feng S K, Li S M, Luo Q Y and Fu H Z 2011 Adv. Mater. Res. 197 1109
|
[19] |
Fleurial J P, Gailliard L, Triboulet R, Scherrer H and Scherrer S 1988 J. Phys. Chem. Solids 49 1237
|
[20] |
Snyder G J and Toberer E S 2008 Nat. Mater. 7 105
|
[21] |
Paolo G, Stefano B, Nicola B, et al. 2009 J. Phys.: Condens. Matter 21 395502
|
[22] |
Perdew J P, Burke K and Ernzerhof M 1996 Phys. Rev. Lett. 77 3865
|
[23] |
Vanderbilt D 1990 Phys. Rev. B 41 7892
|
[24] |
Liu D C and Nocedal J 1989 Math. Program. 45 503
|
[25] |
Madsen G K H and Singh D J 2006 Comput. Phys. Commun. 175 67
|
[26] |
Dantzig J A and Rappaz M 2009 Solidification (Switzerland: EPFL Press) p. 305
|
[27] |
Chitroub M, Scherrer S and Scherrer H 2000 J. Phys. Chem. Solid. 61 1693
|
[28] |
Ainsworth L 1956 P. Phys. Soc. B 69 606
|
[29] |
Stefanescu D M 2008 Science and Engineering of Casting Solidification (New York: Springer) p. 137
|
[30] |
Scherrer H and Scherrer S 2006 Thermoelectrics Handbook: Macro to Nano (CRC Press: Taylor & Francis Group) p. 16
|
[31] |
Stern F 1980 Phys. Rev. Lett. 44 1469
|
[32] |
Vining C B 1991 J. Appl. Phys. 69 331
|
[33] |
Sootsman J R, Kong H J, Uher C, D'Angelo J J, Wu C I, Hogan T P, Caillat T and Kanatzidis M G 2008 Angew. Chem. 120 8746
|
[34] |
Ramu A T, Cassels L E, Hackman N H, Lu H, Zide J M O and Bowers J E 2010 J. Appl. Phys. 107 083707
|
[35] |
Pichanusakorn P and Bandaru P R 2009 Appl. Phys. Lett. 94 223108
|
[36] |
Wang S Y, Tan G J, Xie W J, Zheng G, Li H, Yang J H and Tang X F 2012 J. Mater. Chem. 22 20943
|
[37] |
Satterthwaite C B and Ure R W 1957 Phy. Rev. 108 1164
|
[38] |
Takashiri M, Miyazaki K, Tanaka S, Kurosaki J, Nagai D and Tsukamoto H 2008 J. Appl. Phys. 104 084302
|
[39] |
Chernatynskiy A and Phillpot S R 2013 Curr. Opin. Solid State Mater. Sci. 17 1
|
[40] |
Qiu B and Ruan X L 2009 Phys. Rev. B 80 165203
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
Altmetric
|
blogs
Facebook pages
Wikipedia page
Google+ users
|
Online attention
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.
View more on Altmetrics
|
|
|