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Chin. Phys. B, 2014, Vol. 23(10): 107805    DOI: 10.1088/1674-1056/23/10/107805
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor

Wang Yan-Ze (王延泽), Ma Jian (马健), Sun Liang (孙亮), Li Rui (李蕊), Wang Da-Jian (王达健)
Institute of Materials Physics, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
Abstract  The photoluminescence properties and energy transfer of a new Ce3+/Pr3+/Eu3+ co-doped solid-solution composition of Sr2.975-xLaxAlO4+xF1-x (LSAF) phosphor are investigated. Upon doping Pr3+ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of 1D23H4. Addition of Eu3+ to LSAF:Ce3+, Pr3+ phosphor results in a sharp emission peaked at 675 nm for the 5D07F3 transition and an increase of the intensity of red emission for Pr3+ with increasing Eu3+ concentration. The pathways of energy transfer among Ce3+, Pr3+, and Eu3+ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.
Keywords:  energy transfer      solid solution      red emission      phosphor  
Received:  07 March 2014      Revised:  22 April 2014      Accepted manuscript online: 
PACS:  78.55.-m (Photoluminescence, properties and materials)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 21076161 and 50872091).
Corresponding Authors:  Wang Da-Jian     E-mail:  djwang@tjut.edu.cn
About author:  78.55.-m

Cite this article: 

Wang Yan-Ze (王延泽), Ma Jian (马健), Sun Liang (孙亮), Li Rui (李蕊), Wang Da-Jian (王达健) Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor 2014 Chin. Phys. B 23 107805

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