Controlling the photoluminescence spectroscopy of quinacrine dihydrochloride by SiO2 inverse opal photonic crystal

doi:10.1088/1674-1056/22/12/124201

Abstract Manipulation of the photoluminescence spectra of light-emitting materials doped in three-dimensional (3D) inverse opal photonic crystals is investigated. Quinacrine dihydrochloride molecules doped highly ordered SiO₂ inverse opal is successfully synthesized by co-assembly combined with double-substrate vertical infiltrate method. The quinacrine dihydrochloride-doped and-undoped SiO₂ inverse opals each exhibit an apparent photonic band gap (PBG) in the visible light region. Significant suppression of the emission is observed when the PBG is overlapped with the quinacrine dihydrochloride emission bands. The mechanism of suppression effect of PBG in inverse opal on the fluorescence intensity of quinacrine dihydrochloride molecules is studied.

Keywords: inverse opals photonic stop band photoluminescence

Received: 16 January 2013
Revised: 13 March 2013
Accepted manuscript online:

PACS:	42.25.-p	(Wave optics)
	68.65.-k	(Low-dimensional, mesoscopic, nanoscale and other related systems: structure and nonelectronic properties)
	78.66.-w	(Optical properties of specific thin films)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 91122022 and 51172209) and the Natural Science Foundation of Zhejiang Province of of China (Grant No. LR12E02001).

Corresponding Authors: Li Chao-Rong
E-mail: crli@zstu.edu.cn

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Li Chao-Rong (李超荣), Yang Zhao-Ting (杨诏婷), Xu Qing (徐庆), Dong Wen-Jun (董文钧) Controlling the photoluminescence spectroscopy of quinacrine dihydrochloride by SiO₂ inverse opal photonic crystal 2013 Chin. Phys. B 22 124201

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Controlling the photoluminescence spectroscopy of quinacrine dihydrochloride by SiO2 inverse opal photonic crystal

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Controlling the photoluminescence spectroscopy of quinacrine dihydrochloride by SiO₂ inverse opal photonic crystal