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Phosphine-free synthesis of FeTe2 nanoparticles and self-assembly into tree-like nanoarchitectures |
Hongyu Wang(王红宇)1,2, Min Wu(武敏)1, Yixuan Wang(王艺璇)1, Hao Wang(王浩)2, Xiaoli Huang(黄晓丽)1, Xinyi Yang(杨新一)1 |
1 State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China; 2 College of Material Science and Engineering, Jilin Jianzhu University, Changchun 130118, China |
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Abstract Manipulating the self-assembly of transition metal telluride nanocrystals (NCs) creates opportunities for exploring new properties and device applications. Iron ditelluride (FeTe2) has recently emerged as a new class of magnetic semiconductor with three-dimensional (3D) magnetic ordering and narrow band gap structure, yet the self-assembly of FeTe2 NCs has not been achieved. Herein, the tree-like FeTe2 nanoarchitectures with orthorhombic crystal structure have been successfully synthesized by hot-injection solvent thermal approach using phosphine-free Te precursor. The morphology, size, and crystal structure have been investigated using transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and powder x-ray diffraction (XRD). We study the formation process of tree-like FeTe2 NCs according to trace the change of the sample morphology with the reaction time. It was found that the FeTe2 nanoparticles show oriented aggregation and self-assembly behavior with the increase of reaction time, which is attributed to size-dependent magnetism properties of the samples. The magnetic interaction is thought to be the driving force of nanoparticle self-organization.
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Received: 14 June 2019
Revised: 30 July 2019
Accepted manuscript online:
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PACS:
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64.75.Yz
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(Self-assembly)
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81.07.-b
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(Nanoscale materials and structures: fabrication and characterization)
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Fund: Project supported by the National Natural Science Foundation of China (Grant No. 11874027) and the China Postdoctoral Science Foundation (Grant Nos. 2019T120233 and 2017M621198). |
Corresponding Authors:
Xiaoli Huang, Xinyi Yang
E-mail: huangxiaoli@jlu.edu.cn;yangxinyi@jlu.edu.cn
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Cite this article:
Hongyu Wang(王红宇), Min Wu(武敏), Yixuan Wang(王艺璇), Hao Wang(王浩), Xiaoli Huang(黄晓丽), Xinyi Yang(杨新一) Phosphine-free synthesis of FeTe2 nanoparticles and self-assembly into tree-like nanoarchitectures 2019 Chin. Phys. B 28 106401
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