Structure instability-induced high dielectric properties in[001]-oriented 0.68Pb(Mg1/3Nb2/3)O3-0.33PbTiO3 crystals

doi:10.1088/1674-1056/28/5/057701

Abstract The structure evolution and origin of ultrahigh dielectric properties have been investigated in the low temperature range from 300 K to 5 K for[001]-oriented 0.68Pb(Mg_1/3Nb_2/3)O₃-0.33PbTiO₃ (PMN-33PT) crystal. The experimental results reveal that a short-range ordered monoclinic M_A is the dominant phase at ambient temperature. As the temperature drops below 270 K, the M_A transforms into monoclinic M_C, and the M_C remains stable until 5 K. Although no phase transition occurs from 5 K to 245 K, polar nanoregions (PNRs) display visible changes. The instability of PNRs is suggested as responsible for the low temperature relaxation. The ultrahigh dielectric constant at room temperature is associated with the instability of local structure and phase transition. Our research provides an insight into the design of high-performance ferroelectric materials.

Keywords: ferroelectric crystal phase transition local structure dielectric properties

Received: 17 January 2019
Revised: 21 February 2019
Accepted manuscript online:

PACS:	77.84.-s	(Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)
	77.80.B-	(Phase transitions and Curie point)
	75.78.Fg	(Dynamics of domain structures)
	87.19.rf	(Dielectric properties)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51602242 and 51472197) and the Natural Science Basic Research Plan in Shaanxi Province of China (Grant No. 2018JM5097).

Corresponding Authors: Xiao-Juan Li
E-mail: lixiaojuan28@163.com

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Xiao-Juan Li(李晓娟), Xing Fan(樊星), Zeng-Zhe Xi(惠增哲), Peng Liu(刘鹏), Wei Long(龙伟), Pin-Yang Fang(方频阳), Rui-Hua Nan(南瑞华) Structure instability-induced high dielectric properties in[001]-oriented 0.68Pb(Mg_1/3Nb_2/3)O₃-0.33PbTiO₃ crystals 2019 Chin. Phys. B 28 057701

[1]	Li F, Zhang S, Xu Z and Chen L 2017 Adv. Funct. Mater. 27 1700310
[2]	Wang R, Xu H, Yang B, Luo Z, Sun E, Zhao J, Zheng L, Dong Y, Zhou H, Ren Y and Cao W 2016 Appl. Phys. Lett. 108 152905
[3]	Kim K, Paynea D and Zuo J 2013 J. Appl. Cryst. 46 1331
[4]	Xu G, Wen J, Stock C and Gehring P M 2008 Nat. Mater. 7 562
[5]	Li F, Zhang S, Yang T, Xu Z, Zhang N, Liu G, Wang J, Wang J, Cheng Z, Ye Z, Luo J, Shrout T R and Chen L 2016 Nat. Commun. 7 13807
[6]	Li F, Lin D B, Chen Z B, Cheng Z X, Wang J L, Li C C, X Z, Huang Q W, Liao X Z, Chen L Q, Shrout T R and Zhang S J 2018 Nat. Mater. 17 349
[7]	Tan H X, Takenaka H, Xu C S, Duan W H, Grinberg I and Rappe A M 2018 Phys. Rev. B 97 174101
[8]	Harby A E, Hannora A E and El-Desoky M M 2019 J. Alloys Compound 770 906
[9]	Xu C, Li Q, Yan Q, Luo N, Zhang Y and Chu X 2016 J. Am. Ceram. Soc. 99 2706
[10]	Xu G, Luo H, Xu H and Yin Z 2001 Phys. Rev. B 64 020102(R)
[11]	Zheng L, Lu X, Shang H, Xi Z, Wang R, Wang J, Zheng P and Cao W 2015 Phys. Rev. B 91 184105
[12]	Bao P, Yan F, Lu X, Zhu J, Shen H, Wang Y and Luo H 2006 Appl. Phys. Lett. 88 092905
[13]	Wan Y, Li Z, Ma M, Li F, Xu Z, Fan S and Yao X 2014 J. Adv. Dielect. 4 1450004
[14]	Yang Y, Zhang L, Zhu M and Liu Y 2011 J. Appl. Phys. 109 083517
[15]	Noheda B, Cox D, Shirane G, Gao J and Ye Z G 2002 Phys. Rev. B 66 054104
[16]	Bai F, Wang N, Li J, Viehl, D, Gehring P M, Xu G and Shirane G 2004 J. Appl. Phys. 96 1620
[17]	Yang Y, Liu L, Zhang Y, Zhu K, Ma S, Siu G G, Xu Z and Luo H 2010 J. Raman Spectrosc. 41 1735
[18]	Slodczyk A, Daniel P and Kania A 2008 Phys. Rev. B 77 184114
[19]	Li F, Zhang S J, Xu Z, Wei X Y, Luo J and Shrout T R 2010 J Appl. Phys. 108 034106
[20]	Dietze M, Katzke H, Souni M E, Neumann N and Luo H S 2012 Appl. Phys. Lett. 100 242905
[21]	Priya S, Viehl D and Uchino K 2002 Appl. Phys. Lett. 80 4217
[22]	Stock C, Van Eijck L, Fouquet P, Maccarini M, Gehring P M, Xu G, Luo H, Zhao X, Li J F and Viehland D 2010 Phys. Rev. B 81 144127
[23]	Li F, Zhang S J, Damjanovic D, Chen L Q and Shrout T R 2018 Adv. Funct. Mater. 28 1801504
[24]	Svitelskiy O, Toulouse J and Ye Z 2003 Phys. Rev. B 68 104107
[25]	Marssi M E and Dammak H 2007 Solid State Commun. 142 487
[26]	Manley M, Lynn J, Abernathy D, Specht E D, Delaire O, Bishop A R, Sahul R and Buda J D 2014 Nat. Commun. 5 3683
[27]	Luo N N, Zhang, S J, Li Q, Yan Q F, Zhang Y L, Ansell T, Luo J and Shrout T R 2016 J. Mater. Chem. C 4 4568

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Structure instability-induced high dielectric properties in[001]-oriented 0.68Pb(Mg1/3Nb2/3)O3-0.33PbTiO3 crystals

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Structure instability-induced high dielectric properties in[001]-oriented 0.68Pb(Mg_1/3Nb_2/3)O₃-0.33PbTiO₃ crystals