Bismuth-content-dependent polarized Raman spectrum of InPBi alloy

doi:10.1088/1674-1056/25/6/066301

Abstract

We systematically investigate the optical properties of the InP_1-xBi_x ternary alloys with 0≤ x≤ 2.46%, by using high resolution polarized Raman scattering measurement. Both InP-like and InBi-like optical vibration modes (LO) are identified in all the samples, suggesting that most of the Bi-atoms are incorporated into the lattice sites to substitute P-atoms. And the intensity of the InBi-like Raman mode is positively proportional to the Bi-content. Linear red-shift of the InP-like longitudinal optical vibration mode is observed to be 1.1 cm^-1/Bi%, while that of the InP-like optical vibration overtone (2LO) is nearly doubled. In addition, through comparing the Z(XX)Z and Z(XY)Z Raman spectra, longitudinal-optical-plasmon-coupled (LOPC) modes are identified in all the samples, and their intensities are found to be proportional to the electron concentrations.

Keywords: InPBi Raman spectra red-shift LOPC modes

Received: 28 January 2016
Revised: 07 March 2016
Accepted manuscript online:

PACS:	63.20.-e	(Phonons in crystal lattices)
	63.20.kd	(Phonon-electron interactions)
	63.20.dd	(Measurements)

Fund:

Project supported by the National Basic Research Program of China (Grant No. 2014CB643903) and the National Natural Science Foundation of China (Grant Nos. 61225021, 11474272, and 11174272).

Corresponding Authors: Kai-You Wang
E-mail: kywang@semi.ac.cn

Cite this article:

Guan-Nan Wei(魏冠男), Qing-Hai Tan(谭青海), Xing Dai(戴兴), Qi Feng(冯琦), Wen-Gang Luo(骆文刚), Yu Sheng(盛宇), Kai Wang(王凯), Wen-Wu Pan(潘文武), Li-Yao Zhang(张立瑶), Shu-Min Wang(王庶民), Kai-You Wang(王开友) Bismuth-content-dependent polarized Raman spectrum of InPBi alloy 2016 Chin. Phys. B 25 066301

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Bismuth-content-dependent polarized Raman spectrum of InPBi alloy

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