Effect of chloride introduction on the optical properties in Eu3+-doped fluorozirconate glasses

doi:10.1088/1674-1056/25/10/103201

Abstract Fluorozirconate glass containing Eu³⁺ ions and chloride ions are prepared by a meltquenching method. The luminescence behavior of Eu³⁺ affected by Cl ions is investigated. With increasing Cl ion concentration, the luminous intensity of Eu³⁺ is significantly enhanced and the quantum efficiency of fluorozirconate glass is improved. Meanwhile, the intensity parameter Ω₂ increases according to the Judd-Ofelt calculation, which indicates the decrease of local symmetry. The average lifetime of Eu³⁺ increases by introducing the Cl ions. Moreover, we find two kinds of sites for Eu³⁺ ions in a glass network by analyzing the fluorescence decay. The distribution of Eu³⁺ ions changes with increasing Cl ion concentration. In addition, the excessive Cl ions lead to the separation of the glass phase and the formation of the crystal phase, thus reducing the transmittance dramatically.

Keywords: photoluminescence fluorescence decay Judd-Ofelt theory quantum efficiency

Received: 04 February 2016
Revised: 23 May 2016
Accepted manuscript online:

PACS:	32.50.+d	(Fluorescence, phosphorescence (including quenching))
	66.30.hh	(Glasses)

Fund: Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA014201), the Natural Science Foundation of Tianjin, China (Grant Nos. 14JCZDJC31200, 15JCYBJC16700, and 15JCYBJC16800), the National Key Foundation for Exploring Scientific Instrument of China (Grant No. 2014YQ120351), and the International Cooperation Program from Science and Technology of Tianjin, China (Grant No. 14RCGHGX00872).

Corresponding Authors: Zhao-Jun Mo, Lan Li
E-mail: mzjmzj163@163.com;lilan@tjut.edu.cn

Cite this article:

Han Jin(金含), Zhao-Jun Mo(莫兆军), Xiao-Song Zhang(张晓松), Lin-Lin Yuan(苑琳琳), Ming Yan(晏明), Lan Li(李岚) Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses 2016 Chin. Phys. B 25 103201

[1]	Sun J, Zhang X S, Yuan L L, Feng Z J, Ling Z and Li L 2014 Chin. Phys. B 23 114103
[2]	Wang T S, Duan B H, Tian F, Peng H B, Chen L, Zhang L M and Yuan W 2015 Chin. Phys. B 24 076102
[3]	Li Q Y, Xu X H, Zhang B H, Wu Y M, Qiu J B and Yu X 2014 Chin. Phys. B 23 127803
[4]	Merigeon J, Maalej O, Boulard B, Stanculescu A, Leontie L, Mardare D and Girtan M 2015 Opt. Mater. 48 243
[5]	Lachheb R, Damak K, Assadi A A, Herrmann A, Yousef E, Rüssel C and Maâlej R 2015 J. Lumin. 161 281
[6]	Pfau C, Bohley C, Miclea P T and Schweizer S 2011 J. Appl. Phycol. 109 083545
[7]	Bendow B, Banerjee P K, Drexhage M G, Goltman J, Mitra S S and Moynihan C T 1982 J. Am. Chem. Soc. 65 C8
[8]	Bendow B, Drexhage M G and Lipson H G 1981 J. Appl. Phys. 52 1460
[9]	Inoue S, Soga K and Makishima A 1993 J. Am. Chem. Soc. 76 1591
[10]	Ahrens B, Brand S, Büchner T, Darr P, Schoenfelder S, Paßlick C and Schweizer S 2011 J. Non-Cryst. Solids 357 2264
[11]	Poulain M 1983 J. Non-Cryst. Solids 56 1
[12]	Soga K, Inoue H and Makishima A 2000 J. Non-Cryst. Solids 274 69
[13]	Edgar A, Schweizer S, Assmann S, Spaeth J M, Newman P J and MacFarlane D R 2001 J. Non-Cryst. Solids 284 237
[14]	Yu C, Zhang J, Wang G and Jiang Z H 2008 J. Alloys Compd. 461 378
[15]	Hendy S C and Edgar A 2006 J. Non-Cryst. Solids 352 415
[16]	Rajesh D, Brahmachary K, Ratnakaram Y C, Kiran N, Baker A P and Wang G G 2015 J. Alloys Compd. 646 1096
[17]	Fan S, Yu C, He D, Li K and Hu L 2012 J. Alloys Compd. 518 80
[18]	Pisarski W A, Zur L, Kowal M and Pisarska J 2015 J. Alloys Compd. 651 565
[19]	Maalej O, EI Jouad M, Gaumer N, Chaussedent S, Boulard B and Dammak Ben Ameur M, Dammak Ben Tijani D 2015 J. Non-Cryst. Solids 420 48
[20]	Kalpana T, Brik M G, Sudarsan V, Naresh P, Ravi Kumar V, Kityk I V and Veeraiah N 2015 J. Non-Cryst. Solids 419 75
[21]	Tian Y, Xu R, Hu L and Zhang J 2012 J. Lumin. 132 128
[22]	Soga K and Inoue H and Makishima A 1993 J. Lumin. 55 17

[1]	Thermally enhanced photoluminescence and temperature sensing properties of Sc₂W₃O₁₂:Eu³⁺ phosphors Yu-De Niu(牛毓德), Yu-Zhen Wang(汪玉珍), Kai-Ming Zhu(朱凯明), Wang-Gui Ye(叶王贵), Zhe Feng(冯喆), Hui Liu(柳挥), Xin Yi(易鑫), Yi-Huan Wang(王怡欢), and Xuan-Yi Yuan(袁轩一). Chin. Phys. B, 2023, 32(2): 028703.
[2]	Growth behaviors and emission properties of Co-deposited MAPbI₃ ultrathin films on MoS₂ Siwen You(游思雯), Ziyi Shao(邵子依), Xiao Guo(郭晓), Junjie Jiang(蒋俊杰), Jinxin Liu(刘金鑫), Kai Wang(王凯), Mingjun Li(李明君), Fangping Ouyang(欧阳方平), Chuyun Deng(邓楚芸), Fei Song(宋飞), Jiatao Sun(孙家涛), and Han Huang(黄寒). Chin. Phys. B, 2023, 32(1): 017901.
[3]	Enhanced photoluminescence of monolayer MoS₂ on stepped gold structure Yu-Chun Liu(刘玉春), Xin Tan(谭欣), Tian-Ci Shen(沈天赐), and Fu-Xing Gu(谷付星). Chin. Phys. B, 2022, 31(8): 087803.
[4]	Exploration of structural, optical, and photoluminescent properties of (1-x)NiCo₂O₄/xPbS nanocomposites for optoelectronic applications Zein K Heiba, Mohamed Bakr Mohamed, Noura M Farag, and Ali Badawi. Chin. Phys. B, 2022, 31(6): 067801.
[5]	Effect of different catalysts and growth temperature on the photoluminescence properties of zinc silicate nanostructures grown via vapor-liquid-solid method Ghfoor Muhammad, Imran Murtaza, Rehan Abid, and Naeem Ahmad. Chin. Phys. B, 2022, 31(5): 057801.
[6]	Exciton luminescence and many-body effect of monolayer WS₂ at room temperature Jian-Min Wu(吴建民), Li-Hui Li(黎立辉), Wei-Hao Zheng(郑玮豪), Bi-Yuan Zheng(郑弼元), Zhe-Yuan Xu(徐哲元), Xue-Hong Zhang(张学红), Chen-Guang Zhu(朱晨光), Kun Wu(吴琨), Chi Zhang(张弛), Ying Jiang(蒋英),Xiao-Li Zhu(朱小莉), and Xiu-Juan Zhuang(庄秀娟). Chin. Phys. B, 2022, 31(5): 057803.
[7]	Magnetic polaron-related optical properties in Ni(II)-doped CdS nanobelts: Implication for spin nanophotonic devices Fu-Jian Ge(葛付建), Hui Peng(彭辉), Ye Tian(田野), Xiao-Yue Fan(范晓跃), Shuai Zhang(张帅), Xian-Xin Wu(吴宪欣), Xin-Feng Liu(刘新风), and Bing-Suo Zou(邹炳锁). Chin. Phys. B, 2022, 31(1): 017802.
[8]	Pressure- and temperature-dependent luminescence from Tm³⁺ ions doped in GdYTaO₄ Peng-Yu Zhou(周鹏宇), Xiu-Ming Dou(窦秀明), Bao-Quan Sun(孙宝权), Ren-Qin Dou(窦仁琴), Qing-Li Zhang(张庆礼), Bao Liu(刘鲍), Pu-Geng Hou(侯朴赓), Kai-Lin Chi(迟凯粼), and Kun Ding(丁琨). Chin. Phys. B, 2022, 31(1): 017101.
[9]	Controllable preparation and disorder-dependent photoluminescence of morphologically different C₆₀ microcrystals Wen Cui(崔雯), De-Jun Li(李德军), Jin-Liang Guo(郭金良), Lang-Huan Zhao(赵琅嬛), Bing-Bing Liu(刘冰冰), and Shi-Shuai Sun(孙士帅). Chin. Phys. B, 2021, 30(8): 086101.
[10]	Optical spectroscopy study of damage evolution in 6H-SiC by H$_{2}^{ + }$ implantation Yong Wang(王勇), Qing Liao(廖庆), Ming Liu(刘茗), Peng-Fei Zheng(郑鹏飞), Xinyu Gao(高新宇), Zheng Jia(贾政), Shuai Xu(徐帅), and Bing-Sheng Li(李炳生). Chin. Phys. B, 2021, 30(5): 056106.
[11]	Combined effects of carrier scattering and Coulomb screening on photoluminescence in InGaN/GaN quantum well structure with high In content Rui Li(李睿), Ming-Sheng Xu(徐明升), Peng Wang(汪鹏), Cheng-Xin Wang(王成新), Shang-Da Qu(屈尚达), Kai-Ju Shi(时凯居), Ye-Hui Wei(魏烨辉), Xian-Gang Xu(徐现刚), and Zi-Wu Ji(冀子武). Chin. Phys. B, 2021, 30(4): 047801.
[12]	Optical polarization characteristics for AlGaN-based light-emitting diodes with AlGaN multilayer structure as well layer Lu Xue(薛露), Yi Li(李毅), Mei Ge(葛梅), Mei-Yu Wang(王美玉), and You-Hua Zhu(朱友华). Chin. Phys. B, 2021, 30(4): 047802.
[13]	Microstructure, optical, and photoluminescence properties of β -Ga₂O₃ films prepared by pulsed laser deposition under different oxygen partial pressures Rui-Rui Cui(崔瑞瑞), Jun Zhang(张俊), Zi-Jiang Luo(罗子江), Xiang Guo(郭祥), Zhao Ding(丁召), and Chao-Yong Deng(邓朝勇). Chin. Phys. B, 2021, 30(2): 028505.
[14]	Crystal growth, spectral properties and Judd-Ofelt analysis of Pr: CaF₂-YF₃ Jie Tian(田杰), Xiao Cao(曹笑), Wudi Wang(王无敌), Jian Liu(刘坚), Jianshu Dong(董建树), Donghua Hu(胡冬华), Qingguo Wang(王庆国), Yanyan Xue(薛艳艳), Xiaodong Xu(徐晓东), and Jun Xu(徐军). Chin. Phys. B, 2021, 30(10): 108101.
[15]	Exciton emissions of CdS nanowire array fabricated on Cd foil by the solvothermal method Yong Li(李勇), Peng-Fei Ji(姬鹏飞), Ya-Juan Hao(郝亚娟), Yue-Li Song(宋月丽), Feng-Qun Zhou(周丰群), and Shu-Qing Yuan(袁书卿). Chin. Phys. B, 2021, 30(1): 016104.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Effect of chloride introduction on the optical properties in Eu3+-doped fluorozirconate glasses

Cite this article:

Online attention

Effect of chloride introduction on the optical properties in Eu³⁺-doped fluorozirconate glasses