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Chin. Phys. B, 2015, Vol. 24(5): 056101    DOI: 10.1088/1674-1056/24/5/056101
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

Structure and chemical valence study of Srn+1RunO3n+1 (n=1, 2, ∞) series

Zheng Long (郑龙), Zhu Xiao-Qin (朱小芹), Sui Yong-Xing (眭永兴), Xue Jian-Zhong (薛建忠), Liu Bo (刘波), Pei Ming-Xu (裴明旭)
School of Mathematics and Physics, Jiangsu University of Technology, Changzhou 213001, China
Abstract  Effect of structure parameter n and its coupling with the connection mode among RuO6 octahedra of Srn+1RunO3n+1 (n=1, 2, ∞) are investigated. The gradually enhanced rotation and tilting effect with increasing n are observed in Srn+1RunO3n+1. Besides, the chemical valence of Ru is not changed, while the one of Sr gradually varies with increasing n, which highlights the great contribution of connection mode to the chemical environment. Our results show a strong n dependence on the connection mode between octahedra in Srn+1RunO3n+1 (n=1, 2, ∞).
Keywords:  ruthenates      structure parameter      x-ray diffraction      extended x-ray absorption fine structure  
Received:  13 November 2014      Revised:  17 December 2014      Accepted manuscript online: 
PACS:  61.05.cp (X-ray diffraction)  
  78.70.Ck (X-ray scattering)  
Corresponding Authors:  Zheng Long     E-mail:  zhengphy@163.com
About author:  61.05.cp; 78.70.Ck

Cite this article: 

Zheng Long (郑龙), Zhu Xiao-Qin (朱小芹), Sui Yong-Xing (眭永兴), Xue Jian-Zhong (薛建忠), Liu Bo (刘波), Pei Ming-Xu (裴明旭) Structure and chemical valence study of Srn+1RunO3n+1 (n=1, 2, ∞) series 2015 Chin. Phys. B 24 056101

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