Stereodynamics study of reactions N(2D)+HD→NH+D and ND+H
Yue Xian-Fang(岳现房)a)†, Cheng Jie(程杰)a), Li Hong(李宏)a), Zhang Yong-Qiang(张永强)a), and Emilia L. Wub)
a Department of Physics and Information Engineering, Jining University, Qufu 273155, China; b Department of Chemical Engineering and Materials Science, 421 Washington Avenue SE, Minneapolis, Minnesota 55455, USA
AbstractThe product polarizations of the title reactions are investigated by employing the quasi-classical trajectory (QCT) method. The four generalized polarization-dependent differential cross-sections (PDDCSs) , , , and are calculated in the centre-of-mass frame. The distribution of the angle between and , , the distribution of the dihedral angle denoting correlation, , as well as the angular distribution of product rotational vectors in the form of polar plots are calculated. The isotope effect is also revealed and primarily attributed to the difference in mass factor between the two title reactions.
Fund: Project supported by Young Funding
of Jining University, China (Grant No.~2009QNKJ02).
Cite this article:
Yue Xian-Fang(岳现房), Cheng Jie(程杰), Li Hong(李宏), Zhang Yong-Qiang(张永强), and Emilia L. Wu Stereodynamics study of reactions N(2D)+HD→NH+D and ND+H 2010 Chin. Phys. B 19 043401
[1]
Han K L and He G Z 2007 J. Photochem. Photobiol. C: Photochem. Rev. 8 55
[2]
Liu Y F, Jiang L J, Ma H and Sun J F 2008 Chin. Phys. B 17 1674
[3]
Chu T S, Zhang Y and Han K L 2006 Int. Rev. Phys. Chem. 25 201
[4]
Yan S, Wu Y T, Zhang B, Yue X F and Liu K P 2007 Science 316 1723
[5]
Yue X F, Sun J L, Yin H M, Wei Q and Han K L 2009 J. Phys. Chem. A 113 3303
[6]
Shi D H, Zhang J P, Sun J F, Liu Y F, Zhu Z L, Ma H and Yang X D 2008 Chin. Phys. B 17 3678
[7]
Luo W L, Ruan W, Zhang L, Zhu Z H and Fu Y B 2009 Chin. Phys. B 18 167
[8]
Chi B Q, Liu L and Wang J G 2008 Chin. Phys. B 17 2890
[9]
Chu T S and Han K L 2008 Phys. Chem. Chem. Phys. 10 2431
[10]
Chen M D, Han K L and Lou N Q 2002 Chem. Phys. Lett. 357 483
[11]
Chen M D, Han K L and Lou N Q 2003 J. Chem. Phys. 118 4463
[12]
Ho T S, Rabitz H, Aoiz F J, Ba\{n}ares L, Vázquez S A and Harding L B 2003 J. Chem. Phys. 119 3063
[13]
Varandas A J C and Poveda L A 2006 Theor. Chem. Acc. 116 4
[14]
Qu Z W, Zhu H, Schinke R, Adam L and Hack W 2005 J. Chem. Phys. 122 204313
[15]
Lin S Y and Guo H 2006 J. Chem. Phys. 124 031101
[16]
Chu T S, Han K L and Varandas A J C 2006 J. Phys. Chem. A 110 1666
[17]
Varandas A J C, Chu T S, Han K L and Caridade P J S B 2006 Chem. Phys. Lett. 421 415
[18]
Chu T S, Duan Y B, Yuan S P and Varandas 2007 Chem. Phys. Lett. 444 351
[19]
Castillo J F, Bulut N, Ba\{n}ares L and Gogtas F 2007 Chem. Phys. 332 119
[20]
Rao B J and Mahapatra S 2007 J. Chem. Phys. 127 244307
[21]
Han K L, He G Z and Lou N Q 1996 J. Chem. Phys. 105 8699
[22]
Zhang X and Han K L 2006 Int. J. Quantun Chem. 106 1815
[23]
Han K L, Zhang L, Xu D L, He G Z and Lou N Q 2001 J. Phys. Chem. A 105 2956
[24]
Xu W W, Liu X G, Luan S X, Sun S S and Zhang Q G 2009 Chin. Phys. B 18 339
[25]
Chen M D, Han K L and Lou N Q 2002 Chem. Phys. 283 463
[26]
Ma J J, Chen M D, Cong S L and Han K L 2006 Chem. Phys. 327 529
[27]
Wang M L, Han K L and He G Z 1998 J. Chem. Phys. 109 5446
[28]
Wang M L, Han K L and He G Z 1998 J. Phys. Chem. A 102 20204
[29]
Chen M D, Han K L and Lou N Q 2002 Chem. Phys. Lett. 357 483
[30]
Li R J, Han K L, Li F E, Lu R C, He G Z and Lou N Q 1994 Chem. Phys. Lett. 220 281
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