Influence of N+ implantation on structure, morphology, and corrosion behavior of Al in NaCl solution

doi:10.1088/1674-1056/ab7d97

Abstract Structural and morphological changes as well as corrosion behavior of N⁺ implanted Al in 0.6 M NaCl solution as function of N⁺ fluence are investigated. The x-ray diffraction results confirmed AlN formation. The atomic force microscope (AFM) images showed larger grains on the surface of Al with increasing N⁺ fluence. This can be due to the increased number of impacts of N⁺ with Al atoms and energy conversion to heat, which increases the diffusion rate of the incident ions in the target. Hence, the number of the grain boundaries is reduced, resulting in corrosion resistance enhancement. Electrochemical impedance spectroscopy (EIS) and polarization results showed the increase of corrosion resistance of Al with increasing N⁺ fluence. EIS data was used to simulate equivalent electric circuits (EC) for the samples. Strong dependence of the surface morphology on the EC elements was observed. The scanning electron microscope (SEM) analysis of the samples after corrosion test also showed that the surfaces of the implanted Al samples remain more intact relative to the untreated Al sample, consistent with the EIS and polarization results.

Keywords: aluminium ion implantation surface morphology corrosion electrochemical impedance spectroscopy polarization

Received: 09 December 2019
Revised: 17 February 2020
Accepted manuscript online:

PACS:	81.65.Kn	(Corrosion protection)
	82.45.Bb	(Corrosion and passivation)
	52.77.Dq	(Plasma-based ion implantation and deposition)
	61.05.cp	(X-ray diffraction)

Corresponding Authors: Hadi Savaloni
E-mail: savaloni@khayam.ut.ac.ir

Cite this article:

Hadi Savaloni, Rezvan Karami, Helma Sadat Bahari, Fateme Abdi Influence of N⁺ implantation on structure, morphology, and corrosion behavior of Al in NaCl solution 2020 Chin. Phys. B 29 058102

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Influence of N+ implantation on structure, morphology, and corrosion behavior of Al in NaCl solution

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Influence of N⁺ implantation on structure, morphology, and corrosion behavior of Al in NaCl solution