Phase transition and near-zero thermal expansion of Zr0.5Hf0.5VPO7

doi:10.1088/1674-1056/27/6/066501

Abstract The Zr_0.5Hf_0.5VPO₇ is successfully synthesized by the solid-state method with near-zero thermal expansion. Powder x-ray diffraction (XRD), Raman spectroscopy, thermal dilatometry, and scanning electron microscopy (SEM) are used to investigate the structure, the phase transition, and the coefficient of thermal expansion (CTE) of Zr_0.5Hf_0.5VPO₇. The investigation results show that the samples are of the single cubic type with a space group of Pa3 at room temperature (RT). It can be inferred that the superstructure is transformed from the 3×3×3 superstructure to the 1×1×1 ideal crystal in a temperature range between 310 K and 323 K. The CTE is measured by a dilatometer to be 0.59×10^-6 K^-1 (310 K-673 K). The values of intrinsic (XRD) and extrinsic (dilatometric) thermal expansion are both near zero. The results show that Zr_0.5Hf_0.5VPO₇ has near-zero thermal expansion behavior over a wide temperature range.

Keywords: near-zero thermal expansion phase transition x-ray diffraction (XRD) Raman spectrum

Received: 09 March 2018
Revised: 22 March 2018
Accepted manuscript online:

PACS:	65.40.De	(Thermal expansion; thermomechanical effects)
	81.05.Je	(Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))
	61.50.-f	(Structure of bulk crystals)
	78.30.-j	(Infrared and Raman spectra)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos.11574276,U173112,and 41401384),the Project of Shandong Provincial Higher Educational Science and Technology Program,China (Grant No.J17KB127),the Science and Technology Development Plans of Binzhou City,China (Grant Nos.2014ZC0307 and 2015ZC0210),and Binzhou University Research Fund Project,China (Grant Nos.BZXYG1513 and BZXYG1706).

Corresponding Authors: You-Wen Liu, Er-Jun Liang
E-mail: ywliu@nuaa.edu.cn;ejliang@zzu.edu.cn

Cite this article:

Jun-Ping Wang(王俊平), Qing-Dong Chen(陈庆东), Sai-Lei Li(李赛磊), Yan-Jun Ji(纪延俊), Wen-Ying Mu(穆文英), Wei-Wei Feng(冯伟伟), Gao-Jie Zeng(曾高杰), You-Wen Liu(刘友文), Er-Jun Liang(梁二军) Phase transition and near-zero thermal expansion of Zr_0.5Hf_0.5VPO₇ 2018 Chin. Phys. B 27 066501

[1]	Yuan B H, Liu X S, Mao Y C, Wang J Q, Guo J, Cheng Y G, Song W B, Liang E J and Chao M J 2016 Mater. Chem. Phys. 170 162
[2]	Dai Y J, Huang R J, Wang W, Li L F and Sun Z H 2017 Ceram. Int. 43 1608
[3]	Ding L, Wang C, Na Y Y, Chu L H and Yan J 2011 Scr. Mater. 65 687
[4]	Yan J, Sun Y, Wang C, Chu L H, Shi Z X, Deng S H, Shi K W and Lu H Q 2014 Scr. Mater. 84-85 19
[5]	Yan X, Cheng X N, Yang X B and Zhang C H 2007 Key Eng. Mater. 353-358 1235
[6]	Yang X B, Cheng X N, Yan X H, Yang J, Fu T B and Qiu J 2007 Compos. Sci. Technol. 1167-1171 67
[7]	Yang X B, Xu J, Li H J, Cheng X N and Yan X H 2007 J. Am. Ceram. Soc. 90 1953
[8]	Romao C P, Perras F A, Wernerzwanziger U, Lussier J A and Miller K J 2015 Chem. Mater. 27 2633
[9]	Liang E J, Liang Y, Zhao Y, Liu J and Jiang Y J 2008 J. Phys. Chem. A 112 12582
[10]	Yuan B H, Liu X S, Mao Y C, Wang J Q, Guo J, Cheng Y G, Song W B, Liang E J and Chao M J 2016 Mater. Chem. Phys. 170 162
[11]	Yanase I, Kojima T and Kobayashi H 2011 Solid State Commun. 151 595
[12]	Mittal R and Chaplot S L 2008 Phys. Rev. B 78 2599
[13]	Yuan H L, Yuan B H, Li F and Liang E J 2012 Acta Phys. Sin. 61 226502 (in Chinese)
[14]	Song W B, Liang E J, Liu X S, Li Z Y, Yuan B H and Wang J Q 2013 Chin. Phys. Lett. 30 126502
[15]	Wu M M, Peng J, Zu Y, Liu Y D, Hu Z B, Liu Y T and Chen D F 2012 Chin. Phys. B 21 116102
[16]	Li Q J, Yuan B H, Song W B, Liang E J and Yuan B 2012 Chin. Phys. B 21 046501
[17]	Hisashige T, Yamaguchi T, Tsuji T and Yamamura Y 2006 J. Ceram. Soc. Jpn. 114 607
[18]	Evans J S O, Hanson J C and Sleight A W 1998 Acta Crystallogr. 54 705
[19]	Xiang H M, Feng Z H and Zhou Y C 2014 J. Eur. Ceram. Soc. 34 1809
[20]	Jiang X R, Molokeev M S, Gong P F, Yang Y, Wang W, Wang S H, et al. 2016 Adv. Mater. 28 7936
[21]	Chen D X, Yuan B H, Cheng Y G, Ge X H, Jia Y, Liang E J, et al. 2016 Phys. Lett. A 380 4070
[22]	Marinkovic B A, Jardim P M, Ari M, Avillez R R D, Rizzo F and Ferreira F F 2008 Phys. Stat. Sol. 245 2514
[23]	Hemamala U L C, El F, Muthu D V S, Krogh A M, Andersen, Carlson S, Ouyang L and Kruger M B 2007 Solid State Commun. 141 680

[1]	Tailoring of thermal expansion and phase transition temperature of ZrW₂O₈ with phosphorus and enhancement of negative thermal expansion of ZrW_1.5P_0.5O_7.75 Chenjun Zhang(张晨骏), Xiaoke He(何小可), Zhiyu Min(闵志宇), and Baozhong Li(李保忠). Chin. Phys. B, 2023, 32(4): 048201.
[2]	Topological phase transition in network spreading Fuzhong Nian(年福忠) and Xia Zhang(张霞). Chin. Phys. B, 2023, 32(3): 038901.
[3]	Liquid-liquid phase transition in confined liquid titanium Di Zhang(张迪), Yunrui Duan(段云瑞), Peiru Zheng(郑培儒), Yingjie Ma(马英杰), Junping Qian(钱俊平), Zhichao Li(李志超), Jian Huang(黄建), Yanyan Jiang(蒋妍彦), and Hui Li(李辉). Chin. Phys. B, 2023, 32(2): 026801.
[4]	Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo₄O₇ Tina Raoufi, Jincheng He(何金城), Binbin Wang(王彬彬), Enke Liu(刘恩克), and Young Sun(孙阳). Chin. Phys. B, 2023, 32(1): 017504.
[5]	Prediction of flexoelectricity in BaTiO₃ using molecular dynamics simulations Long Zhou(周龙), Xu-Long Zhang(张旭龙), Yu-Ying Cao(曹玉莹), Fu Zheng(郑富), Hua Gao(高华), Hong-Fei Liu(刘红飞), and Zhi Ma(马治). Chin. Phys. B, 2023, 32(1): 017701.
[6]	Configurational entropy-induced phase transition in spinel LiMn₂O₄ Wei Hu(胡伟), Wen-Wei Luo(罗文崴), Mu-Sheng Wu(吴木生), Bo Xu(徐波), and Chu-Ying Ouyang(欧阳楚英). Chin. Phys. B, 2022, 31(9): 098202.
[7]	Hard-core Hall tube in superconducting circuits Xin Guan(关欣), Gang Chen(陈刚), Jing Pan(潘婧), and Zhi-Guo Gui(桂志国). Chin. Phys. B, 2022, 31(8): 080302.
[8]	Exchange-coupling-induced fourfold magnetic anisotropy in CoFeB/FeRh bilayer grown on SrTiO₃(001) Qingrong Shao(邵倾蓉), Jing Meng(孟婧), Xiaoyan Zhu(朱晓艳), Yali Xie(谢亚丽), Wenjuan Cheng(程文娟), Dongmei Jiang(蒋冬梅), Yang Xu(徐杨), Tian Shang(商恬), and Qingfeng Zhan(詹清峰). Chin. Phys. B, 2022, 31(8): 087503.
[9]	Effect of f-c hybridization on the $γ \to α$ phase transition of cerium studied by lanthanum doping Yong-Huan Wang(王永欢), Yun Zhang(张云), Yu Liu(刘瑜), Xiao Tan(谈笑), Ce Ma(马策), Yue-Chao Wang(王越超), Qiang Zhang(张强), Deng-Peng Yuan(袁登鹏), Dan Jian(简单), Jian Wu(吴健), Chao Lai(赖超), Xi-Yang Wang(王西洋), Xue-Bing Luo(罗学兵), Qiu-Yun Chen(陈秋云), Wei Feng(冯卫), Qin Liu(刘琴), Qun-Qing Hao(郝群庆), Yi Liu(刘毅), Shi-Yong Tan(谭世勇), Xie-Gang Zhu(朱燮刚), Hai-Feng Song(宋海峰), and Xin-Chun Lai(赖新春). Chin. Phys. B, 2022, 31(8): 087102.
[10]	Characterization of topological phase of superlattices in superconducting circuits Jianfei Chen(陈健菲), Chaohua Wu(吴超华), Jingtao Fan(樊景涛), and Gang Chen(陈刚). Chin. Phys. B, 2022, 31(8): 088501.
[11]	Structural evolution and molecular dissociation of H₂S under high pressures Wen-Ji Shen(沈文吉), Tian-Xiao Liang(梁天笑), Zhao Liu(刘召), Xin Wang(王鑫), De-Fang Duan(段德芳), Hong-Yu Yu(于洪雨), and Tian Cui(崔田). Chin. Phys. B, 2022, 31(7): 076102.
[12]	Universal order-parameter and quantum phase transition for two-dimensional q-state quantum Potts model Yan-Wei Dai(代艳伟), Sheng-Hao Li(李生好), and Xi-Hao Chen(陈西浩). Chin. Phys. B, 2022, 31(7): 070502.
[13]	Structural evolution and bandgap modulation of layered β-GeSe₂ single crystal under high pressure Hengli Xie(谢恒立), Jiaxiang Wang(王家祥), Lingrui Wang(王玲瑞), Yong Yan(闫勇), Juan Guo(郭娟), Qilong Gao(高其龙), Mingju Chao(晁明举), Erjun Liang(梁二军), and Xiao Ren(任霄). Chin. Phys. B, 2022, 31(7): 076101.
[14]	Topological phase transition in cavity optomechanical system with periodical modulation Zhi-Xu Zhang(张志旭), Lu Qi(祁鲁), Wen-Xue Cui(崔文学), Shou Zhang(张寿), and Hong-Fu Wang(王洪福). Chin. Phys. B, 2022, 31(7): 070301.
[15]	Dynamical quantum phase transition in XY chains with the Dzyaloshinskii-Moriya and XZY-YZX three-site interactions Kaiyuan Cao(曹凯源), Ming Zhong(钟鸣), and Peiqing Tong(童培庆). Chin. Phys. B, 2022, 31(6): 060505.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Phase transition and near-zero thermal expansion of Zr0.5Hf0.5VPO7

Cite this article:

Online attention

Phase transition and near-zero thermal expansion of Zr_0.5Hf_0.5VPO₇