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Chin. Phys. B, 2017, Vol. 26(9): 090703    DOI: 10.1088/1674-1056/26/9/090703
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Pressure-induced phase transition of B-type Y2O3

Qian Zhang(张倩)1, Xiang Wu(巫翔)2, Shan Qin(秦善)3
1 Gemological Institute, China University of Geosciences, Wuhan 430074, China;
2 State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China;
3 Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education & School of Earth and Space Sciences, Peking University, Beijing 100871, China
Abstract  The synthesized monoclinic (B-type) phase of Y2O3 has been investigated by in situ angle-dispersive x-ray diffraction in a diamond anvil cell up to 44 GPa at room temperature. A phase transition occurs from monoclinic (B-type) to hexagonal (A-type) phase at 23.5 GPa and these two phases coexist even at the highest pressure. Parameters of isothermal equation of state are V0=69.0(1) Å3, K0=159(3) GPa, K0'=4 (fixed) for the B-type phase and V0=67.8(2) Å3, K0=156(3) GPa, K0'=4 (fixed) for the A-type phase. The structural anisotropy increases with increasing pressure for both phases.
Keywords:  Y2O3      x-ray diffraction      pressure-induced phase transition      equation of state  
Received:  03 May 2017      Revised:  15 May 2017      Published:  05 September 2017
PACS:  07.35.+k (High-pressure apparatus; shock tubes; diamond anvil cells)  
  61.05.cp (X-ray diffraction)  
  91.60.Hg (Phase changes)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. U1232204 and 41502029) and China Postdoctoral Science Foundation (Grant No. 2015M580679).
Corresponding Authors:  Qian Zhang     E-mail:  qianzhang@cug.edu.cn

Cite this article: 

Qian Zhang(张倩), Xiang Wu(巫翔), Shan Qin(秦善) Pressure-induced phase transition of B-type Y2O3 2017 Chin. Phys. B 26 090703

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