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Photothermal-chemical synthesis of P-S-H ternary hydride at high pressures |
| Tingting Ye(叶婷婷)1,2, Hong Zeng(曾鸿)1,2, Peng Cheng(程鹏)1,2, Deyuan Yao(姚德元)1,2, Xiaomei Pan(潘孝美)1,2, Xiao Zhang(张晓)1,3,†, and Junfeng Ding(丁俊峰)1,2,‡ |
1 Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China;
2 University of Science and Technology of China, Hefei 230026, China;
3 Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China |
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Abstract The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted much interest in ternary hydrogen rich materials. In this report, ternary hydride P-S-H was synthesized through a photothermal-chemical reaction from elemental sulfur (S), phosphorus (P) and molecular hydrogen (H2) at high pressures and room temperature. Raman spectroscopy under pressure shows that H2S and PH3 compounds are synthesized after laser heating at 0.9 GPa, and a ternary van der Waals compound P-S-H is synthesized with further compression to 4.6 GPa. The P-S-H compound is probably a mixed alloy of PH3 and (H2S)2H2 with a guest-host structure similar to the C-S-H system. The ternary hydride can persist up to 35.6 GPa at least and shows two phase transitions at approximately 23.6 GPa and 32.8 GPa, respectively.
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Received: 02 December 2021
Revised: 27 January 2022
Accepted manuscript online: 17 February 2022
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PACS:
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74.70.-b
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(Superconducting materials other than cuprates)
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78.30.-j
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(Infrared and Raman spectra)
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82.40.Fp
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(Shock wave initiated reactions, high-pressure chemistry)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 52002372, 51672279, 51727806, 11874361, and 11774354), Science Challenge Project (Grant No. TZ2016001), and Chinese Academy of Sciences Innovation Grant (Grant No. CXJJ-19-B08). |
Corresponding Authors:
Xiao Zhang, Junfeng Ding
E-mail: xiaozhang@issp.ac.cn;junfengding@issp.ac.cn
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Cite this article:
Tingting Ye(叶婷婷), Hong Zeng(曾鸿), Peng Cheng(程鹏), Deyuan Yao(姚德元), Xiaomei Pan(潘孝美), Xiao Zhang(张晓), and Junfeng Ding(丁俊峰) Photothermal-chemical synthesis of P-S-H ternary hydride at high pressures 2022 Chin. Phys. B 31 067402
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[1] Lototskyy M V, Yartys V A, Pollet B G and Bowman R C 2014 International Journal of Hydrogen Energy 39 5818
[2] Ichikawa T, Fujii H, Isobe S and Nabeta K 2005 Appl. Phys. Lett. 86 241914
[3] Xiao X Z, Chen L X, Fan X L, Wang X H, Chen C P, Lei Y Q and Wang Q D 2009 Appl. Phys. Lett. 94 041907
[4] Liu Y, Kanhere P D, Wong C L, Tian Y F, Feng Y H, Boey F, Wu T, Chen H Y, White T J, Chen Z and Zhang Q C 2010 Journal of Solid State Chemistry 183 2644
[5] Zhang X, Fan J, Lu X, Han Z, Cazorla C, Hu L, Wu T and Chu D 2021 Chemical Engineering Journal 415 129048
[6] Ovshinsky S R, Fetcenko M A and Ross J 1993 Science 260 176
[7] Ashcroft N W 2004 Phys. Rev. Lett. 92 187002
[8] Drozdov A P, Eremets M I, Troyan I A, Ksenofontov V and Shylin S I 2015 Nature 525 73
[9] Zhang X, Xu W, Wang Y, Jiang S, Gorelli F A, Greenberg E, Prakapenka V B and Goncharov A F 2018 Phys. Rev. B 97 064107
[10] Geballe Z M, Liu H, Mishra A K, Ahart M, Somayazulu M, Meng Y, Baldini M and Hemley R J 2018 Angewandte Chemie International Edition 57 688
[11] Semenok D V, Kvashnin A G, Ivanova A G, Svitlyk V, Fominski V Y, Sadakov A V, Sobolevskiy O A, Pudalov V M, Troyan I A and Oganov A R 2020 Materials Today 33 36
[12] Drozdov A P, Kong P P, Minkov V S, Besedin S P, Kuzovnikov M A, Mozaffari S, Balicas L, Balakirev F F, Graf D E, Prakapenka V B, Greenberg E, Knyazev D A, Tkacz M and Eremets M I 2019 Nature 569 528
[13] Somayazulu M, Ahart M, Mishra A K, Geballe Z M, Baldini M, Meng Y, Struzhkin V V and Hemley R J 2019 Phys. Rev. Lett. 122 027001
[14] Snider E, Dasenbrock-Gammon N, Mcbride R, Debessai M, Vindana H, Vencatasamy K, Lawler K V, Salamat A and Dias R P 2020 Nature 586 373
[15] Cheng Y, Wang X, Zhang J, Yang K, Niu C and Zeng Z 2019 RSC Advances 9 7680
[16] Errea I, Calandra M, Pickard C J, Nelson J, Needs R J, Li Y, Liu H, Zhang Y, Ma Y and Mauri F 2015 Phys. Rev. Lett. 114 157004
[17] Komelj M and Krakauer H 2015 Phys. Rev. B 92 205125
[18] Einaga M, Sakata M, Ishikawa T, Shimizu K, Eremets M I, Drozdov A P, Troyan I A, Hirao N and Ohishi Y 2016 Nat. Phys. 12 835
[19] Bernstein N, Hellberg C S, Johannes M D, Mazin I I and Mehl M J 2015 Phys. Rev. B 91 060508
[20] Errea I, Calandra M, Pickard C J, Nelson J R, Needs R J, Li Y, Liu H, Zhang Y, Ma Y and Mauri F 2016 Nature 532 81
[21] Heil C and Boeri L 2015 Phys. Rev. B 92 060508
[22] Liu B B, Cui W W, Shi J M, Zhu L, Chen J, Lin S Y, Su R M, Ma J Y, Yang K, Xu M L, Hao J, Durajski A P, Qi J S, Li Y L and Li Y W 2018 Phys. Rev. B 98 8
[23] Amsler M 2019 Phys. Rev. B 99 060102
[24] Chang P H, Silayi S, Papaconstantopoulos D A and Mehl M J 2020 Journal of Physics and Chemistry of Solids 139 109315
[25] Ge Y F, Zhang F and Yao Y G 2016 Phys. Rev. B 93 224513
[26] Strobel T A, Ganesh P, Somayazulu M, Kent P R and Hemley R J 2011 Phys. Rev. Lett. 107 255503
[27] Guigue B, Marizy A and Loubeyre P 2017 Phys. Rev. B 95 020104
[28] Pace E J, Liu X D, Dalladay-Simpson P, Binns J, Peña-Alvarez M, Attfield J P, Howie R T and Gregoryanz E 2020 Phys. Rev. B 101 174511
[29] Bykova E, Bykov M, Chariton S, Prakapenka V B, Glazyrin K, Aslandukov A, Aslandukova A, Criniti G, Kurnosov A and Goncharov A F 2021 Phys. Rev. B 103 L140105
[30] Zhang X 2021 Chin. Phys. B 30 127801
[31] Mao H K, Xu J and Bell P M 1986 Journal of Geophysical Research-Solid Earth and Planets 91 4673
[32] Goncharov A F 2012 International Journal of Spectroscopy 2012 1
[33] Ding J F, Ye T T, Zhang H C, Yang X, Zeng H, Zhang C G and Wang X L 2019 Appl. Phys. Lett. 115 101902
[34] Huang T H, Decius J C and Nibler J W 1977 Journal of Physics and Chemistry of Solids 38 897
[35] Shimizu H, Nakamichi Y and Sasaki S 1991 Journal of Chemical Physics 95 2036
[36] Yuan Y, Li Y, Fang G, Liu G, Pei C, Li X, Zheng H, Yang K and Wang L 2019 National Science Review 6 524
[37] Ceppatelli M, Scelta D, Serrano-Ruiz M, Dziubek K, Garbarino G, Jacobs J, Mezouar M, Bini R and Peruzzini M 2020 Nat. Commun. 11 6125
[38] Gardner M 1973 Journal of the Chemical Society, Dalton Transactions 691
[39] Jensen J O, Zeroka D and Banerjee A 2000 Journal of Molecular Structure-Theochem 505 31
[40] Ji C, Li B, Liu W, Smith J S, Majumdar A, Luo W, Ahuja R, Shu J, Wang J, Sinogeikin S, Meng Y, Prakapenka V B, Greenberg E, Xu R, Huang X, Yang W, Shen G, Mao W L and Mao H K 2019 Nature 573 558
[41] Zhao X, Zhang K, Cao Z, Zhao Z, Struzhkin V V, Goncharov A F, Wang H, Gavriliuk A G, Mao H and Chen X 2020 Phys. Rev. B 101 134506
[42] Pan D and Galli G 2020 Nat. Commun. 11 421
[43] Sun Y, Tian Y F, Jiang B W, Li X, Li H F, Iitaka T, Zhong X and Xie Y 2020 Phys. Rev. B 101 174102
[44] Kim D Y, Scheicher R H, Mao H K, Kang T W and Ahuja R 2010 Proc. Natl. Acad. Sci. USA 107 2793
[45] Tanaka K, Tse J S and Liu H 2017 Phys. Rev. B 96 100502 |
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